中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Microwave-assisted hydrothermal synthesis of hydroxy-sodalite zeolite membrane

文献类型:期刊论文

作者Xu, XC; Bao, Y; Song, CS; Yang, WS; Liu, J; Lin, LW
刊名microporous and mesoporous materials
出版日期2004-11-02
卷号75期号:3页码:173-181
关键词gas separation hydrothermal synthesis hydroxy-sodalite microwave heating zeolite membrane
产权排序1;1
英文摘要a high quality pure hydroxy-sodalite zeolite membrane was successfully synthesized on an alpha-al2o3 support by a novel microwave-assisted hydrothermal synthesis (mars) method. influence of synthesis conditions, such as synthesis time, synthesis procedure, etc., on the formation of hydroxy-sodalite zeolite membrane by mahs method was studied by x-ray diffraction (xrd), scanning electron microscopy (sem) and gas permeation measurements. the synthesis of hydroxy-sodalite zeolite membrane by mahs method only needed 45 min and synthesis was more than 8 times faster than by the conventional hydrothermal synthesis (chs) method. a pure hydroxy-sodalite zeolite membrane was easily synthesized by mahs method, while a zeolite membrane, which consisted of nax zeolite, naa zeolite and hydroxy-sodalite zeolite, was usually synthesized by chs method. the effect of preparation procedures had a dramatic impact on the formation of hydroxy-sodalite zeolite membrane and a single-stage synthesis procedure produced a pure hydroxy-sodalite zeolite membrane. the pure hydroxy-sodalite zeolite membrane synthesized by mars method was found to be well inter-grown and the thickness of the membrane was 6-7 mum. gas permeation results showed that the hydrogen/n-butane permselectivity of the hydroxy-sodalite zeolite membrane was larger than 1000. (c) 2004 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary
研究领域[WOS]chemistry ; science & technology - other topics ; materials science
关键词[WOS]molecular-sieve membranes ; gas permeation properties ; inorganic membranes ; composite membranes ; mfi membranes ; separation ; alpo4-5 ; performance ; irradiation ; crystals
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000224824900001
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/81785]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Penn State Univ, Energy Inst, Clean Fuels & Catalysis Program, University Pk, PA 16802 USA
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Xu, XC,Bao, Y,Song, CS,et al. Microwave-assisted hydrothermal synthesis of hydroxy-sodalite zeolite membrane[J]. microporous and mesoporous materials,2004,75(3):173-181.
APA Xu, XC,Bao, Y,Song, CS,Yang, WS,Liu, J,&Lin, LW.(2004).Microwave-assisted hydrothermal synthesis of hydroxy-sodalite zeolite membrane.microporous and mesoporous materials,75(3),173-181.
MLA Xu, XC,et al."Microwave-assisted hydrothermal synthesis of hydroxy-sodalite zeolite membrane".microporous and mesoporous materials 75.3(2004):173-181.

入库方式: OAI收割

来源:大连化学物理研究所

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