Low-temperature heat capacity and thermodynamic properties of crystalline carboxin (C12H13NO2S)
文献类型：期刊论文
| 作者 | Wang, MH; Tan, ZC; Sun, XH; Xu, F; Kong, LG; Sun, LX; Zhang, T |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2004-03-05 |
| 卷号 | 411期号:2页码:203-209 |
| 关键词 | carboxin heat capacity thermodynamic functions adiabatic calorimetry TG DSC |
| 产权排序 | 1;1 |
| 英文摘要 | carboxin was synthesized and its heat capacities were measured with an automated adiabatic calorimeter over the temperature range from 79 to 380k. the melting point, molar enthalpy (delta(fus)h(m)) and entropy (delta(fus)s(m)) of fusion of this compound were determined to be 365.29 +/- 0.06k, 28.193 +/- 0.09 kj mol(-1) and 77.180 +/- 0.02 j mol(-1) k-1, respectively. the purity of the compound was determined to be 99.55 mol% by using the fractional melting technique. the thermodynamic functions relative to the reference temperature (298.15 k) were calculated based on the heat capacity measurements in the temperature range between 80 and 360 k. the thermal stability of the compound was further investigated by differential scanning calorimetry (dsc) and thermogravimetric (tg) analysis. the dsc curve indicates that the sample starts to decompose at ca. 290degreesc with the peak temperature at 292.7degreesc. the tg-dtg results demonstrate the maximum mass loss rate occurs at 293degreesc corresponding to the maximum decomposition rate. (c) 2003 elsevier b.v all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | differential scanning calorimetry ; purity ; fusion |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000189166000011 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/81939]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.NW Univ Xian, Coll Chem Engn, Xian 710069, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, MH,Tan, ZC,Sun, XH,et al. Low-temperature heat capacity and thermodynamic properties of crystalline carboxin (C12H13NO2S)[J]. thermochimica acta,2004,411(2):203-209. |
| APA | Wang, MH.,Tan, ZC.,Sun, XH.,Xu, F.,Kong, LG.,...&Zhang, T.(2004).Low-temperature heat capacity and thermodynamic properties of crystalline carboxin (C12H13NO2S).thermochimica acta,411(2),203-209. |
| MLA | Wang, MH,et al."Low-temperature heat capacity and thermodynamic properties of crystalline carboxin (C12H13NO2S)".thermochimica acta 411.2(2004):203-209. |
入库方式： OAI收割
来源：大连化学物理研究所
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