Low-temperature heat capacity and standard molar enthalpy of formation of 9-fluorenemethanol (C14H12O)
文献类型：期刊论文
| 作者 | Di, YY; Tan, ZC; Sun, XH; Wang, MH; Xu, F; Liu, YF; Sun, LX; Zhang, HT |
| 刊名 | journal of chemical thermodynamics
 |
| 出版日期 | 2004-02-01 |
| 卷号 | 36期号:2页码:79-86 |
| 关键词 | 9-fluorenemethanol adiabatic calorimetry low-temperature heat capacity enthalpy of fusion standard molar enthalpy of combustion standard molar enthalpy of formation |
| 产权排序 | 1;1 |
| 英文摘要 | low-temperature heat capacities of the 9-fluorenemethanol (c14h12o) have been precisely measured with a small sample automatic adiabatic calorimeter over the temperature range between t = 78 k and t = 390 k. the solid-liquid phase transition of the compound has been observed to be t-fus = (376.567 +/- 0.012) k from the heat-capacity measurements. the molar enthalpy and entropy of the melting of the substance were determined to be delta(fus)h(m) = (26.273 +/- 0.013) kj (.) mol(-1) and delta(fus)s(m) = (69.770 +/- 0.035) j (.) k-1 (.) mol(-1). the experimental values of molar heat capacities in solid and liquid regions have been fitted to two polynomial equations by the least squares method. the constant-volume energy and standard molar enthalpy of combustion of the compound have been determined, delta(c)u(c14h12o, s) = -(7125.56 +/- 4.62) kj (.) mol(-1) and delta(c)h(m)degrees(c14h12o, s) = -(7131.76 +/- 4.62) kj (.) mol(-1), by means of a homemade precision oxygen-bomb combustion calorimeter at t = (298.15 +/- 0.001) k. the standard molar enthalpy of formation of the compound has been derived, delta(f)h(m)degrees (c14h12o, s) = -(92.36 +/- 0.97) kj (.) mol(-1), from the standard molar enthalpy of combustion of the compound in combination with other auxiliary thermodynamic quantities through a hess thermochemical cycle. (c) 2004 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | thermodynamics ; chemistry, physical |
| 研究领域[WOS] | thermodynamics ; chemistry |
| 关键词[WOS] | combustion |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000189024100002 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/81941]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.NW Univ Xian, Coll Chem Engn, Xian 710069, Peoples R China |
| 推荐引用方式 GB/T 7714 | Di, YY,Tan, ZC,Sun, XH,et al. Low-temperature heat capacity and standard molar enthalpy of formation of 9-fluorenemethanol (C14H12O)[J]. journal of chemical thermodynamics,2004,36(2):79-86. |
| APA | Di, YY.,Tan, ZC.,Sun, XH.,Wang, MH.,Xu, F.,...&Zhang, HT.(2004).Low-temperature heat capacity and standard molar enthalpy of formation of 9-fluorenemethanol (C14H12O).journal of chemical thermodynamics,36(2),79-86. |
| MLA | Di, YY,et al."Low-temperature heat capacity and standard molar enthalpy of formation of 9-fluorenemethanol (C14H12O)".journal of chemical thermodynamics 36.2(2004):79-86. |
入库方式： OAI收割
来源：大连化学物理研究所
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