Evidence for perimeter sites over SmOx-modified Rh(100) surface by CO chemisorption
文献类型：期刊论文
| 作者 | Jiang, ZQ; Zhou, WP; Tan, DL; Zhai, RS; Bao, XH |
| 刊名 | surface science
 |
| 出版日期 | 2004-09-10 |
| 卷号 | 565期号:2-3页码:269-278 |
| 关键词 | X-ray photoelectron spectroscopy thermal desorption spectroscopy rhodium carbon monoxide |
| 产权排序 | 1;1 |
| 英文摘要 | smox modified rh(l 0 0) surfaces have been in-situ prepared by depositing metallic sin and subsequently oxidizing under controlled conditions, and the interaction between the lanthanide oxide and transition metal has been characterized by means of x-ray photoelectron spectroscopy (xps) and high-resolution electron-energy-loss spectroscopy (hreels) as well as thermal desorption spectroscopy (tds). as evidenced, the adsorption of co on the modified surfaces shows some different features to the original surface of rh(l 00). the covering of smox blocks some sites on the surface and consequently suppresses adsorption of the typical co species with an uptake at about 500 k, while a novel desorption peak centered at 260 k emerges in the co tds. correspondingly, the xp spectrum exhibits a new c is peak at 287.9 ev and 0 is peak at 532.6 ev. the intensity of the low temperature peak varies with the coverage of smox, which shows an actual correlation to the perimeter sites of smox particles on the surface. (c) 2004 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, condensed matter |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | rare-earth-metals ; carbon-monoxide ; ru(001) surface ; alloy-films ; adsorption ; catalysts ; samarium ; support ; valence ; oxide |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000223878100020 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/82073]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, ZQ,Zhou, WP,Tan, DL,et al. Evidence for perimeter sites over SmOx-modified Rh(100) surface by CO chemisorption[J]. surface science,2004,565(2-3):269-278. |
| APA | Jiang, ZQ,Zhou, WP,Tan, DL,Zhai, RS,&Bao, XH.(2004).Evidence for perimeter sites over SmOx-modified Rh(100) surface by CO chemisorption.surface science,565(2-3),269-278. |
| MLA | Jiang, ZQ,et al."Evidence for perimeter sites over SmOx-modified Rh(100) surface by CO chemisorption".surface science 565.2-3(2004):269-278. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。