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Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane

文献类型:期刊论文

作者Bao, ZR; Li, WZ; Xu, HY; Kieffer, R
刊名catalysis letters
出版日期2004-04-01
卷号94期号:1-2页码:125-129
关键词propane oxidative dehydrogenation Ni-V-O catalysts
产权排序2;2
英文摘要ni - v - o series catalysts for the oxidative dehydrogenation (odh) of propane were prepared and characterized by bet, xrd, h-2- tpr, o-2-tpd-ms and electrical conductivity. at 425 degreesc a c3h6 selectivity of 49.9% was observed on ni0.9v0.1oy at a c3h8 conversion of 19.4%, and the obtained selectivity is almost two times higher than that over nio at the roughly same conversion of c3h8. the mobile oxygen species created by the interaction of nio and v2o5 has been found in the composite catalysts by o-2-tpd-ms and electrical conductivity studies, which seems to be responsible for the enhanced selectivity of the propane oxidative dehydrogenation.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]sb-oxide catalysts ; in-situ ; oxydehydrogenation ; ethane ; butane ; nickel ; redox
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000220217400021
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/82789]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Inner Mongolia Normal Univ, Dept Chem, Huhehaote 010022, Inner Mongolia, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.LERCSI ECPM, F-67087 Strasbourg, France
推荐引用方式
GB/T 7714
Bao, ZR,Li, WZ,Xu, HY,et al. Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane[J]. catalysis letters,2004,94(1-2):125-129.
APA Bao, ZR,Li, WZ,Xu, HY,&Kieffer, R.(2004).Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane.catalysis letters,94(1-2),125-129.
MLA Bao, ZR,et al."Correlation between the characteristics and catalytic performance of Ni-V-O catalysts in oxidative dehydrogenation of propane".catalysis letters 94.1-2(2004):125-129.

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来源:大连化学物理研究所

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