Electrocatalytic properties of Cu-Zr amorphous alloy towards the electrochemical hydrogenation of nitrobenzene
文献类型：期刊论文
| 作者 | Jiang, JH; Zhai, RS; Bao, XH |
| 刊名 | journal of alloys and compounds
 |
| 出版日期 | 2003-05-12 |
| 卷号 | 354期号:1-2页码:248-258 |
| 关键词 | amorphous materials catalysis electrochemical reactions |
| 产权排序 | 1;1 |
| 英文摘要 | the cu-zr amorphous alloy was studied as an electrocatalyst towards the electrochemical hydrogenation of nitrobenzene. the electrocatalyst was activated by chemical etching in hf solution. resulted changes in the morphology, chemical composition and crystalline structure of the electrocatalyst surface were characterised by scanning electron microscopy, x-ray diffraction and auger electron spectroscopy. the electrocatalytic properties of the cu-zr amorphous alloy were assessed by voltammetric measurements. due to the formation and aggregation of zr residue modified cu nanocrystals on the surface caused by the selective dissolution of zr components in the chemical etching, the activated amorphous alloy is an effective electrocatalyst for the electrochemical reduction reaction of nitrobenzene with aniline as the main product. the positive shift of the peak potential and accompanying increase in the value of peak current in voltammograms with increasing cu content and decreasing zr content of the alloy surface in the chemical etching are indicative of improved electrocatalytic activity. (c) 2002 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary ; metallurgy & metallurgical engineering |
| 研究领域[WOS] | chemistry ; materials science ; metallurgy & metallurgical engineering |
| 关键词[WOS] | carbon-dioxide ; p-aminophenol ; electrode ; ti ; reduction ; catalysis ; electroreduction ; dehydrogenation ; activation ; 2-propanol |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000182879800046 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/82793]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, JH,Zhai, RS,Bao, XH. Electrocatalytic properties of Cu-Zr amorphous alloy towards the electrochemical hydrogenation of nitrobenzene[J]. journal of alloys and compounds,2003,354(1-2):248-258. |
| APA | Jiang, JH,Zhai, RS,&Bao, XH.(2003).Electrocatalytic properties of Cu-Zr amorphous alloy towards the electrochemical hydrogenation of nitrobenzene.journal of alloys and compounds,354(1-2),248-258. |
| MLA | Jiang, JH,et al."Electrocatalytic properties of Cu-Zr amorphous alloy towards the electrochemical hydrogenation of nitrobenzene".journal of alloys and compounds 354.1-2(2003):248-258. |
入库方式： OAI收割
来源：大连化学物理研究所
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