Synthesis and spectroscopic study of mesoporous aluminum methylphosphonate foam templated by dibutyl methylphosphonate
文献类型：期刊论文
| 作者 | Wu, ZB; Liu, ZM; Tian, P; He, YL; Xu, L; Liu, XM; Bao, XH; Liu, XC |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2003-08-14 |
| 卷号 | 62期号:1-2页码:61-71 |
| 关键词 | aluminum methylphosphonate dibutyl methylphosphonate foam mesoporous template |
| 产权排序 | 1;1 |
| 英文摘要 | new types of templates and novel interactive mechanisms between template and framework are very important for creating porous materials. in this work, by using neutral dibutyl methylphosphonate as a template, an inorganic-organic hybrid mesoporous material, aluminum methylphosphonate, was prepared. the as-synthesized material was studied by p-31 magnetic angle spinning nuclear magnetic resonance (mas nmr), al-27 mas nmr, c-13 cp/mas, ft-ir spectroscopy, thermogravimetry (tg), differential thermal analysis (dta), and transmission electron microscopy. after thermal treatment at 673 k and 10 mmhg for 2 h, hybrid mesoporous foam was obtained. the transformation process was investigated by ft-ir. tg-dta results indicate that the methyl group bonded to the framework keeps intact up to 792 k under air and 823 k under nitrogen. the characterization results from nitrogen gas adsorption-desorption measurements show that the bet surface area and the barrett-joyner-halenda desorption cumulative pore volume of the foam are 90 m(2) g(-1) and 0.32 cm(3) g(-1) respectively. (c) 2003 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | lined unidimensional channels ; metal-organic framework ; almepo-alpha ; dimethyl methylphosphonate ; co-condensation ; hybrid ; silica ; mcm-41 ; beta ; transformation |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000184626000006 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/83027]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Nat Gas Utilizat & Appl Catalysis Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, ZB,Liu, ZM,Tian, P,et al. Synthesis and spectroscopic study of mesoporous aluminum methylphosphonate foam templated by dibutyl methylphosphonate[J]. microporous and mesoporous materials,2003,62(1-2):61-71. |
| APA | Wu, ZB.,Liu, ZM.,Tian, P.,He, YL.,Xu, L.,...&Liu, XC.(2003).Synthesis and spectroscopic study of mesoporous aluminum methylphosphonate foam templated by dibutyl methylphosphonate.microporous and mesoporous materials,62(1-2),61-71. |
| MLA | Wu, ZB,et al."Synthesis and spectroscopic study of mesoporous aluminum methylphosphonate foam templated by dibutyl methylphosphonate".microporous and mesoporous materials 62.1-2(2003):61-71. |
入库方式： OAI收割
来源：大连化学物理研究所
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