Capillary electrochromatographic separation of enantiomers on chemically bonded type of cellulose derivative chiral stationary phases with a positively charged spacer
文献类型：期刊论文
| 作者 | Chen, XM; Jin, WH; Qin, F; Liu, YQ; Zou, HF; Guo, BC |
| 刊名 | electrophoresis
 |
| 出版日期 | 2003-08-01 |
| 卷号 | 24期号:15页码:2559-2566 |
| 关键词 | capillary electrochromatography cellulose derivative chiral stationary phase |
| 产权排序 | 1;1 |
| 英文摘要 | positively charged chiral stationary phases (csps) were prepared for capillary electrochromatography (cec) separation of enantiomers by chemically immobilizing cellulose derivatives onto diethylenetriaminopropylated silica (deaps) with tolylene-2,4-diisocyanate (tdi) as a spacer reagent. anodic electroosmotic mobility was observed in both nonaqueous and aqueous mobile phases due to the positively charged amines on the surface of the prepared csps. for comparison, the traditionally used 3-aminopropyl silica (aps) was also adopted as the base material instead of deaps to prepare csp. it was observed that the eof on the deaps-based csp was 18%-60% higher than that on the aps-based csp under nonaqueous mobile phase conditions. separation of enantiomers in cec was performed on the positively charged csps with the nonaqueous mobile phases of pure ethanol or mixture of hexane-alcohol and the aqueous phases of acetonitrile-water or 95% ethanol. fast separation of enantiomers was achieved on the newly prepared csps. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | performance liquid-chromatography ; silica-gel ; enantioseparations ; size ; tris(3,5-dichlorophenylcarbamate) ; pore |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000184932400019 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/83423]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog R&A Ctr, Dalian 116011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, XM,Jin, WH,Qin, F,et al. Capillary electrochromatographic separation of enantiomers on chemically bonded type of cellulose derivative chiral stationary phases with a positively charged spacer[J]. electrophoresis,2003,24(15):2559-2566. |
| APA | Chen, XM,Jin, WH,Qin, F,Liu, YQ,Zou, HF,&Guo, BC.(2003).Capillary electrochromatographic separation of enantiomers on chemically bonded type of cellulose derivative chiral stationary phases with a positively charged spacer.electrophoresis,24(15),2559-2566. |
| MLA | Chen, XM,et al."Capillary electrochromatographic separation of enantiomers on chemically bonded type of cellulose derivative chiral stationary phases with a positively charged spacer".electrophoresis 24.15(2003):2559-2566. |
入库方式： OAI收割
来源：大连化学物理研究所
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