Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors
文献类型：期刊论文
| 作者 | Liu, CQ; Xu, Y; Liao, SJ; Yu, DR |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2000-06-20 |
| 卷号 | 157期号:1-2页码:253-259 |
| 关键词 | catalytic hollow-fiber reactor polymer-anchored mono- and bimetallic catalysts synergic effect selective hydrogenation cyclopentadiene |
| 英文摘要 | the mono- and bimetallic catalytic polymeric hollow-fiber reactors were established with catalytic polymeric cellulose acetate (ca) hollow fibers prepared by supporting the polymer-anchored mono- or bimetallic catalyst in/on the inner wall of the hollow fibers. the selective hydrogenation of cyclopentadiene to cyclopentene was efficiently carried out in the above catalytic polymeric hollow-fiber reactors, especially in the nabh4 reduced bimetallic pvp-pd-0.5co/ca hollow-fiber reactor under mild conditions of 40 degrees c and 0.1 mpa. it was found that there was a remarkable synergic effect of palladium and cobalt reduced by nabh4 in the bimetallic pvp-pd-0.5co/ca hollow-fiber reactor, which results in a 97.5% conversion of cyclopentadiene and a 98.4% selectivity for cyclopentene. (c) 2000 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | membrane reactor ; palladium-ruthenium ; conjugated dienes ; pervaporation ; oxidation |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000087952600031 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/83933]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Xu, Y,Liao, SJ,et al. Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors[J]. journal of molecular catalysis a-chemical,2000,157(1-2):253-259. |
| APA | Liu, CQ,Xu, Y,Liao, SJ,&Yu, DR.(2000).Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors.journal of molecular catalysis a-chemical,157(1-2),253-259. |
| MLA | Liu, CQ,et al."Selective hydrogenation of cyclopentadiene in mono- and bimetallic catalytic hollow-fiber reactors".journal of molecular catalysis a-chemical 157.1-2(2000):253-259. |
入库方式： OAI收割
来源：大连化学物理研究所
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