Cleavage Information of Mono-Saccharide Derivatives with Electrospray Mass Spectrometry
文献类型：期刊论文
| 作者 | Sun Xue-Jun1; Sun Zhi-Wei2; Hu Bao-Jun1; Sheng Xiao1; You Jin-Mao1,2 |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2008-10-01 |
| 卷号 | 36期号:10页码:1309-1315 |
| 关键词 | High performance liquid chromatography-mass spectrometry pre-column derivatization monosaccharides 1-(2-naphthyl)-3-methyl-5-pyrazolone |
| 英文摘要 | studies on the ms cleavage information of mono-carbohydrate derivatives using the labeling reagent 1-(2-naphthyl) -3-methyl-5-pyrazolone (nmp) coupled with liquid chromatography/electrospray ionization mass spectrometry(lc-esi-ms) are reported. carbohydrate derivatives show sufficient ionization information under esi-ms in positive-ion mode. an intense protonated molecular ion at m/z [m + h](+) and characteristic fragment ion at m/z 473.0 can be used for the accurately qualitative analysis of carbohydrates. no interferences for all aliphatic and aromatic aldehydes presented in natural environmental samples were observed clue to the highly specific parent mass-to-charge ratio and the characteristic fragment ions. the results from esi-ms experiments, especially involving the characteristic fragment ions for the accurately qualitative analysis of carbohydrate derivatives, were emphasized. the carbohydrates from the hydrolyzed rape bee pollen sample including mannose, galacturonic acid, glucuronic acid, rhamnose, glucose, galactose, xylose, arabinose and fucose can successfully be identified. it will be possible to develop a promising esi-ms technique for carbohydrate analysis. the developed method for the identification of carbohydrate compositions is very accurate and reliable. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | performance liquid-chromatography ; 1-phenyl-3-methyl-5-pyrazolone derivatives ; oligosaccharides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000260694900001 |
| 源URL | [http://ir.nwipb.ac.cn/handle/363003/6884]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 作者单位 | 1.Qufu Normal Univ, Coll Chem Sci, Key Lab Life Ogan Anal, Qufu 273165, Peoples R China 2.Chinese Acad Sci, NW Plateau Inst Biol, Xining 810001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun Xue-Jun,Sun Zhi-Wei,Hu Bao-Jun,et al. Cleavage Information of Mono-Saccharide Derivatives with Electrospray Mass Spectrometry[J]. chinese journal of analytical chemistry,2008,36(10):1309-1315. |
| APA | Sun Xue-Jun,Sun Zhi-Wei,Hu Bao-Jun,Sheng Xiao,&You Jin-Mao.(2008).Cleavage Information of Mono-Saccharide Derivatives with Electrospray Mass Spectrometry.chinese journal of analytical chemistry,36(10),1309-1315. |
| MLA | Sun Xue-Jun,et al."Cleavage Information of Mono-Saccharide Derivatives with Electrospray Mass Spectrometry".chinese journal of analytical chemistry 36.10(2008):1309-1315. |
入库方式： OAI收割
来源：西北高原生物研究所
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