Rare-earth-metal mixed hydride/aryloxide complexes bearing mono(cyclopentadienyl) ligands. Synthesis, CO2 fixation, and catalysis on copolymerization of CO2 with cyclohexene oxide
文献类型：期刊论文
| 作者 | Cui DM ; Nishiura M ; Tardif O ; Hou ZM* |
| 刊名 | organometallics
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:11页码:2428-2435 |
| ISSN号 | 0276-7333 |
| 关键词 | RING-OPENING POLYMERIZATION ASYMMETRIC ALTERNATING COPOLYMERIZATION ORGANOYTTRIUM HYDRIDE CHEMISTRY AMIDO-CYCLOPENTADIENYL LIGAND CARBON-DIOXIDE INSERTION DIIMINATE ZINC CATALYSTS SINGLE-SITE CATALYSTS RAY CRYSTAL-STRUCTURE PROPYLENE-OXIDE EPSILON-CAPROLACTONE |
| 通讯作者 | cui dm |
| 中文摘要 | hydrogenolysis of mono(cyclopentadienyl)-ligated rare-earth-metal bis(alkyl) complexes cp'ln-(ch2sime3)2(thf) (ln = y (1a), dy (1b), lu (1c); cp' = c5me4sime3) with phsih3 afforded the mixed hydride/alkyl complexes [cp'ln(mu-h)(ch2sime3)(thf)](2) (ln = y (2a), dy (2b), lu (2c)). the overall structure of complexes 2a-c is a c-2-symmetric dimer containing a planar symmetric ln(2)h(2) core at the center of the molecule. deprotonation of aroh (ar = c6h2-bu-t(2)-2,6-me-4) by the metal alkyl group of 2a-c led to formation of the mixed hydride/aryloxide derivatives [cp'ln(mu-h)(oar)](2) (ln = y (3a), dy (3b), lu (3c)), which adopt the dimeric structure through hydride bridges with trans-accommodated terminal aryloxide groups. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2010-04-14 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/9759]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cui DM,Nishiura M,Tardif O,et al. Rare-earth-metal mixed hydride/aryloxide complexes bearing mono(cyclopentadienyl) ligands. Synthesis, CO2 fixation, and catalysis on copolymerization of CO2 with cyclohexene oxide[J]. organometallics,2008,27(11):2428-2435. |
| APA | Cui DM,Nishiura M,Tardif O,&Hou ZM*.(2008).Rare-earth-metal mixed hydride/aryloxide complexes bearing mono(cyclopentadienyl) ligands. Synthesis, CO2 fixation, and catalysis on copolymerization of CO2 with cyclohexene oxide.organometallics,27(11),2428-2435. |
| MLA | Cui DM,et al."Rare-earth-metal mixed hydride/aryloxide complexes bearing mono(cyclopentadienyl) ligands. Synthesis, CO2 fixation, and catalysis on copolymerization of CO2 with cyclohexene oxide".organometallics 27.11(2008):2428-2435. |
入库方式： OAI收割
来源：长春应用化学研究所
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