Impact of carbon dioxide pressurization on liquid phase organic reactions: A case study on Heck and Diels-Alder reactions
文献类型：期刊论文
| 作者 | Fujita S ; Tanaka T ; Akiyama Y ; Asai K ; Hao J ; Zhao F ; Arai M* |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2008 |
| 卷号 | 350期号:10页码:1615-1625 |
| 关键词 | PALLADIUM CATALYSTS HIGH-PRESSURE SUPERCRITICAL CONDITIONS SELECTIVE HYDROGENATION CO2-EXPANDED SOLVENTS METHYL ACRYLATE SILICA-GEL CO2 MEDIA HYDROFORMYLATION |
| ISSN号 | 1615-4150 |
| 通讯作者 | arai m |
| 中文摘要 | heck coupling reactions of methyl acrylate with various aryl bromides have been investigated using a pd/tpp catalyst in toluene under pressurized co2 conditions up to 13 mpa. although co2 is not a reactant, the pressurization of the reaction liquid phase with co2 has positive and negative impacts on the rate of heck coupling depending on the structures of the substrates examined. in the case of either 2-bromoacetophenone or 2-bromocinnamate, the conversion has a maximum at a co2 pressure of about 3 mpa; for the former, it is much larger by a factor of 3 compared with that under ambient pressure. for 2-bromobenzene, in contrast, the conversion is minimized at a similar co2 pressure, being half compared with that at ambient pressure |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000257596700026 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/9851]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fujita S,Tanaka T,Akiyama Y,et al. Impact of carbon dioxide pressurization on liquid phase organic reactions: A case study on Heck and Diels-Alder reactions[J]. advanced synthesis & catalysis,2008,350(10):1615-1625. |
| APA | Fujita S.,Tanaka T.,Akiyama Y.,Asai K.,Hao J.,...&Arai M*.(2008).Impact of carbon dioxide pressurization on liquid phase organic reactions: A case study on Heck and Diels-Alder reactions.advanced synthesis & catalysis,350(10),1615-1625. |
| MLA | Fujita S,et al."Impact of carbon dioxide pressurization on liquid phase organic reactions: A case study on Heck and Diels-Alder reactions".advanced synthesis & catalysis 350.10(2008):1615-1625. |
入库方式： OAI收割
来源：长春应用化学研究所
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