Axially dissymmetric chiral (R)-N,N'-Bis (2-hydroxy-3,5-ditert-butyl-arylmethyl)-1,1'-binaphthalene-2,2'-diamine as chiral ligands in the reaction of diethylzincto aldehydes.
文献类型：期刊论文
| 作者 | Shi M(施敏) ; Duan WL(段伟良) ; Rong GB(荣国斌) |
| 刊名 | Chin. J. Chem.
 |
| 出版日期 | 2002 |
| 卷号 | 20期号:11页码:1319-1325 |
| 其他题名 | 具有轴手性的联萘胺salen-型手性配体在醛和二乙基锌不对称加成中的应用 |
| 通讯作者 | 施敏 |
| 英文摘要 | Chiral ligand (R)-N-N'-bis(2-hydroxy-3,5-di-tert-butyl-arylmethyl)-1,1'-binaphthalene-2,2'diamine derived from the reduction of schiff base (R)-2,2'-bis (3,5-di-tert-butyl-2-hydroxybenzylideneamino)-1,1'-binaphthyl with LiAIH^4 is fairly effctive in the asymmetric addition reaction of dietylzinc to aldehydes by which good yields (46%-94%) of the corresponding sec-alcohols can be obtained in moderat ee (51%-79%) with R configuration for a variety of aldehydes. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.20020201127 |
| 语种 | 英语 |
| 公开日期 | 2013-01-09 |
| 源URL | [http://202.127.28.38/handle/331003/9808]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Shi M,Duan WL,Rong GB. Axially dissymmetric chiral (R)-N,N'-Bis (2-hydroxy-3,5-ditert-butyl-arylmethyl)-1,1'-binaphthalene-2,2'-diamine as chiral ligands in the reaction of diethylzincto aldehydes.[J]. Chin. J. Chem.,2002,20(11):1319-1325. |
| APA | Shi M,Duan WL,&Rong GB.(2002).Axially dissymmetric chiral (R)-N,N'-Bis (2-hydroxy-3,5-ditert-butyl-arylmethyl)-1,1'-binaphthalene-2,2'-diamine as chiral ligands in the reaction of diethylzincto aldehydes..Chin. J. Chem.,20(11),1319-1325. |
| MLA | Shi M,et al."Axially dissymmetric chiral (R)-N,N'-Bis (2-hydroxy-3,5-ditert-butyl-arylmethyl)-1,1'-binaphthalene-2,2'-diamine as chiral ligands in the reaction of diethylzincto aldehydes.".Chin. J. Chem. 20.11(2002):1319-1325. |
入库方式： OAI收割
来源：上海有机化学研究所
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