Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases
文献类型：期刊论文
| 作者 | Shen YM(沈玉梅) ; Duan WL(段伟良) ; Shi M(施敏) |
| 刊名 | Eur. J. Org. Chem.
 |
| 出版日期 | 2004 |
| 期号 | 14页码:3080-3089 |
| 其他题名 | 席夫碱和苯酚以及有机碱共催化的CO2固定反应研究 |
| 通讯作者 | 施敏 |
| 英文摘要 | Binaphthyldiamino, ethyldiamino and cyclohexyldiamino Schiff bases can catalyze the reaction of epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases to give the corresponding cyclic carbonates in high yields. The simplest binaphthyldiamino Schiff base, derived from the reaction of binaphthyldiamine with salicylaldehyde, gave the highest yield of cyclic carbonate. This catalytic system can be further simplified by use of a phenol instead of the Schiff base to give the corresponding cyclic carbonates in high yields as well. Mechanistic insights were obtained based on a deuterium labeling experiment. The reaction of aziridines with CO2 and epoxide with CS2 were also examined under the same reaction conditions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004). |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/ejoc.200400083 |
| 语种 | 英语 |
| WOS记录号 | WOS:000222894900015 |
| 公开日期 | 2013-01-09 |
| 源URL | [http://202.127.28.38/handle/331003/9914]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Shen YM,Duan WL,Shi M. Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases[J]. Eur. J. Org. Chem.,2004(14):3080-3089. |
| APA | Shen YM,Duan WL,&Shi M.(2004).Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases.Eur. J. Org. Chem.(14),3080-3089. |
| MLA | Shen YM,et al."Chemical fixation of carbon dioxide co-catalyzed by a combination of Schiff bases or phenols and organic bases".Eur. J. Org. Chem. .14(2004):3080-3089. |
入库方式： OAI收割
来源：上海有机化学研究所
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