Bronsted acid-mediated ring-opening reactions of methylenecyclopropanes: a dramatic counter ion effect.
文献类型：期刊论文
| 作者 | Shao LX(邵黎雄) ; Huang JW(黄金文) ; Shi M(施敏) |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2004 |
| 卷号 | 60期号:51页码:11895-11901 |
| 其他题名 | 布郎斯特酸催化的亚甲基环丙烷开环反应研究 |
| 通讯作者 | 施敏 |
| 英文摘要 | We report herein two different ring-opening patterns of methylenecyclopropanes (MCPs) in the presence of two Bronsted acids heptadecafluorooctane-1-sulfonic acid (C8F17SO3H) and toluene p-sulfonic acid (TsOH) under mild conditions: (a) the ring-opening of MCPs by H2O and subsequent etherification give the corresponding homoallylic ethers in the presence of heptadecafluorooctane-1-sulfonic acid; (b) the direct ring-opening of MCPs by the Bronsted acid gives the corresponding homoallylic alcohol derivatives in the presence of toluene p-sulfonic acid. (C) 2004 Elsevier Ltd. All rights reserved. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tet.2004.09.105 |
| 语种 | 英语 |
| 公开日期 | 2013-01-09 |
| 源URL | [http://202.127.28.38/handle/331003/9948]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Shao LX,Huang JW,Shi M. Bronsted acid-mediated ring-opening reactions of methylenecyclopropanes: a dramatic counter ion effect.[J]. Tetrahedron,2004,60(51):11895-11901. |
| APA | Shao LX,Huang JW,&Shi M.(2004).Bronsted acid-mediated ring-opening reactions of methylenecyclopropanes: a dramatic counter ion effect..Tetrahedron,60(51),11895-11901. |
| MLA | Shao LX,et al."Bronsted acid-mediated ring-opening reactions of methylenecyclopropanes: a dramatic counter ion effect.".Tetrahedron 60.51(2004):11895-11901. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。