Separation of ethyl acetate-ethanol azeotropic mixture using hydrophilic ionic liquids
文献类型：期刊论文
| 作者 | Zhang DL ; Deng YF ; Li CB ; Chen J |
| 刊名 | industrial & engineering chemistry research
 |
| 出版日期 | 2008 |
| 卷号 | 47期号:6页码:1995－2001 |
| ISSN号 | 0888-5885 |
| 关键词 | INVERSE GAS-CHROMATOGRAPHY THERMODYNAMIC PROPERTIES ACTIVITY-COEFFICIENTS INFINITE DILUTION 1-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE TRANSPIRATION METHOD PHASE-EQUILIBRIA BINARY-MIXTURES MOLTEN-SALTS WATER |
| 通讯作者 | chen j |
| 中文摘要 | the separation of ethyl acetate and ethanol (etoh) is important but difficult due to their close boiling points and formation of an azeotropic mixture. the separation of the azeotropic mixture of ethyl acetate and etoh using the hydrophilic ionic liquids (ils) 1-alkyl-3-methylimidazolium chloride (alkyl = butyl, hexyl, and octyl) ([c(n)mim]cl, n = 4, 6, 8) and 1-allyl-3-methylimidazolium chloride and bromide ([amim]cl and [amim]br) has been investigated. triangle phase diagrams of five ils with ethyl acetate and etoh were constructed, and the biphasic regions were found as follows: [amim]cl > [amim]br > [c(4)mim]cl > [c(6)mim]cl > [c(8)mim]cl. the mechanisms of the ils including cation, anion, and polarity effect were discussed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000253947600030 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10265]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang DL,Deng YF,Li CB,et al. Separation of ethyl acetate-ethanol azeotropic mixture using hydrophilic ionic liquids[J]. industrial & engineering chemistry research,2008,47(6):1995－2001. |
| APA | Zhang DL,Deng YF,Li CB,&Chen J.(2008).Separation of ethyl acetate-ethanol azeotropic mixture using hydrophilic ionic liquids.industrial & engineering chemistry research,47(6),1995－2001. |
| MLA | Zhang DL,et al."Separation of ethyl acetate-ethanol azeotropic mixture using hydrophilic ionic liquids".industrial & engineering chemistry research 47.6(2008):1995－2001. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。