Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes
文献类型:期刊论文
作者 | Dai LZ(戴伦治) ; Qi MJ(齐明娟) ; Shi YL(时永灵) ; Liu XG(刘旭光) ; Shi M(施敏) |
刊名 | Org. Lett.
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出版日期 | 2007 |
卷号 | 9期号:16页码:3191-3194 |
其他题名 | 金催化的串联成环反应: 高区域和高非对映选择性的水和醇同环氧炔烃的加成反应 |
通讯作者 | 施敏 |
英文摘要 | [GRAPHICS] We have developed a novel access to ketal skeletons through a highly regio- and diastereoselective intermolecular addition of water and alcohols to alkynyl epoxides catalyzed by gold(I). This procedure involves a domino three-membered ring-opening, 6-exo-cycloisomerization, and subsequent intra- or intermolecular nucleophilic addition to a double-bond sequence. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ol0713640 |
语种 | 英语 |
WOS记录号 | WOS:000248315900059 |
公开日期 | 2013-01-09 |
源URL | [http://202.127.28.38/handle/331003/10092] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Dai LZ,Qi MJ,Shi YL,et al. Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes[J]. Org. Lett.,2007,9(16):3191-3194. |
APA | Dai LZ,Qi MJ,Shi YL,Liu XG,&Shi M.(2007).Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes.Org. Lett.,9(16),3191-3194. |
MLA | Dai LZ,et al."Gold(I)-Catalyzed cascade cyclization reaction: Highly regio- and diastereoselective intermolecular addition of water and alcohols to epoxy alkynes".Org. Lett. 9.16(2007):3191-3194. |
入库方式: OAI收割
来源:上海有机化学研究所
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