Lewis acid catalyzed reactions of methylenecyclopropylcarbinols with acetals for the construction of 3-oxabicyclo[3.1.0]hexane derivatives
文献类型:期刊论文
作者 | Shao LX(邵黎雄) ; Shi M(施敏) |
刊名 | Tetrahedron
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出版日期 | 2010 |
卷号 | 66期号:25页码:4551-4554 |
其他题名 | 路易斯酸催化的亚甲基环丙烷醇和缩醛的环加成反应-3-oxabicyclo[3.1.0]hexane的构建 |
通讯作者 | 施敏 |
英文摘要 | Reactions of methylenecyclopropylcarbinols 1 with acetals 2 in the presence of Lewis acid Sc(OPf)(3) produce the ring-closure products 3-oxabicyclo[3.1.0]hexane in moderate to high total yields along with the products in trans-configuration as the sole or major one. The plausible reaction mechanism has been discussed, which is based on the Prins-type reaction mechanism. (C) 2010 Elsevier Ltd. All rights reserved. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tet.2010.04.072 |
语种 | 英语 |
WOS记录号 | WOS:000278947100020 |
公开日期 | 2013-01-09 |
源URL | [http://202.127.28.38/handle/331003/10366] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Shao LX,Shi M. Lewis acid catalyzed reactions of methylenecyclopropylcarbinols with acetals for the construction of 3-oxabicyclo[3.1.0]hexane derivatives[J]. Tetrahedron,2010,66(25):4551-4554. |
APA | Shao LX,&Shi M.(2010).Lewis acid catalyzed reactions of methylenecyclopropylcarbinols with acetals for the construction of 3-oxabicyclo[3.1.0]hexane derivatives.Tetrahedron,66(25),4551-4554. |
MLA | Shao LX,et al."Lewis acid catalyzed reactions of methylenecyclopropylcarbinols with acetals for the construction of 3-oxabicyclo[3.1.0]hexane derivatives".Tetrahedron 66.25(2010):4551-4554. |
入库方式: OAI收割
来源:上海有机化学研究所
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