中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and properties of novel polyimides from sulfonated binaphthalene dianhydride for proton exchange membranes

文献类型:期刊论文

作者Li NW ; Cui ZM ; Zhang SB ; Li SH
刊名journal of polymer science part a-polymer
出版日期2008
卷号46期号:8页码:2820-2832
关键词FUEL-CELL APPLICATIONS POLYMER ELECTROLYTE MEMBRANES C COUPLING REACTION WATER STABILITY CONDUCTING MEMBRANES BLOCK COPOLYIMIDES FLUORENYL GROUPS ACID GROUPS COPOLYMERS POLYBENZIMIDAZOLE
ISSN号0887-624x
通讯作者zhang sb
中文摘要a sulfonated dianhydride monomer, 6,6-disulfonic-4,4'-binaphthyl-1,1',8,8'-tetracarboxylic dianhydride (sbtda), was successfully synthesized by direct sulfonation of the parent dianhydride, 4,4'-binaphthyl-1,1',8,8'-tetracarboxylic dianhydride (btda), using fuming sulfuric acid as the sulfonating reagent. a series of sulfonated homopolyimides were prepared from sbtda and various common nonsulfonated diamines. the resulting polymer electrolytes, which contain ion conductivity sites on the deactivated positions of the aryl backbone rings, displayed high proton conductivities of 0.25-0.31 s cm(-1) at 80 degrees c. the oxidative stability test indicated that the attachment of the -so3h groups onto the dianhydride units did not deteriorate the oxidative stability of the spi membranes.
收录类别SCI
语种英语
WOS记录号WOS:000254978600022
公开日期2010-04-14
源URL[http://ir.ciac.jl.cn/handle/322003/10297]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Li NW,Cui ZM,Zhang SB,et al. Synthesis and properties of novel polyimides from sulfonated binaphthalene dianhydride for proton exchange membranes[J]. journal of polymer science part a-polymer,2008,46(8):2820-2832.
APA Li NW,Cui ZM,Zhang SB,&Li SH.(2008).Synthesis and properties of novel polyimides from sulfonated binaphthalene dianhydride for proton exchange membranes.journal of polymer science part a-polymer,46(8),2820-2832.
MLA Li NW,et al."Synthesis and properties of novel polyimides from sulfonated binaphthalene dianhydride for proton exchange membranes".journal of polymer science part a-polymer 46.8(2008):2820-2832.

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来源:长春应用化学研究所

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