Highly regio- and stereoselective synthesis of polysubstituted cyclopropane compounds via the Pd(O)-catalyzed coupling-cyclization reaction of 2-(2 ',3 '-allenyl)malonates with organic halides
文献类型:期刊论文
作者 | Ma SM(麻生明) ; Jiao N(焦宁) ; Yang Q(杨青) ; Zheng ZL(郑子龙) |
刊名 | J. Org. Chem.
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出版日期 | 2004 |
卷号 | 69期号:19页码:6463-6466 |
ISSN号 | 0022-3263 |
其他题名 | 钯催化的2-(2',3 联烯基)丙二酸酯与卤化物的偶联关环反应高区域及立体选择性合成多取代环丙烷 |
通讯作者 | 麻生明 |
英文摘要 | A new method for highly regio- and stereoselective synthesis of polysubstituted cyclopropane compounds via the Pd(0)-catalyzed coupling-cyclization reaction of 2-(2',3'-allenyl)malonates with organic halides is described. In these reactions, the starting materials are easily available and the operation is convenient. The ratios of trans-isomer/ cis-vinylic cyclopropanes are up to 98:2. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/jo049323u |
语种 | 英语 |
WOS记录号 | WOS:000223897700037 |
公开日期 | 2013-01-15 |
源URL | [http://202.127.28.38/handle/331003/11956] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Ma SM,Jiao N,Yang Q,et al. Highly regio- and stereoselective synthesis of polysubstituted cyclopropane compounds via the Pd(O)-catalyzed coupling-cyclization reaction of 2-(2 ',3 '-allenyl)malonates with organic halides[J]. J. Org. Chem.,2004,69(19):6463-6466. |
APA | 麻生明,焦宁,杨青,&郑子龙.(2004).Highly regio- and stereoselective synthesis of polysubstituted cyclopropane compounds via the Pd(O)-catalyzed coupling-cyclization reaction of 2-(2 ',3 '-allenyl)malonates with organic halides.J. Org. Chem.,69(19),6463-6466. |
MLA | 麻生明,et al."Highly regio- and stereoselective synthesis of polysubstituted cyclopropane compounds via the Pd(O)-catalyzed coupling-cyclization reaction of 2-(2 ',3 '-allenyl)malonates with organic halides".J. Org. Chem. 69.19(2004):6463-6466. |
入库方式: OAI收割
来源:上海有机化学研究所
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