Ligand effect on the insertion reactions of allenes with MHCl(CO)(PPh3)(3)and MHCl(PPh3)(3) (M = Ru, Os)
文献类型：期刊论文
| 作者 | Bai T(白涛) ; Zhu J(朱俊) ; Xue P(薛彭) ; Ho-Yung Sung ; Ian Duncan Williams ; Ma SM(麻生明) ; Li ZY(李震杨) ; Jia GC(贾国成) |
| 刊名 | Organometallics
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:23页码:5581-5589 |
| ISSN号 | 0276-7333 |
| 其他题名 | Ligand effect on the insertion reactions of allenes with MHCl(CO)(PPh3)(3)and MHCl(PPh3)(3) (M = Ru, Os) |
| 通讯作者 | 麻生明 ; 李震杨 ; 贾国成 |
| 英文摘要 | Treatment of RuHCl(CO)(PPh3)(3) with CH2=C=CHCO2Me gives the allyl complex Ru(77 3 -CH2CHCHCO2Me)CI(CO)(PPh3)(2). The analogous allyl complexes Os(eta(3)-CH2CHCHR)Cl(CO)(PPh3)(2) (R = Ph, CH2Ph) are also produced from the reactions of OsHCI(CO)(PPh3)(3) with CH2=C=CHR. In contrast, MHCl(PPh3)(3) (M = Ru, Os) react with CH2=C=CHR to give the vinyl complexes MCl((C(CH3)=CHR)(CH2 C=CHR)(PPh3)(2) (M = Ru, R = CMe3, M = Os, R = CMe3, Ph, CO2Et). The difference in the reaction pathways for the reactions of allenes with MHCl(CO)(PPh3)(3) and MHCl(PPh3)(3) (M = Ru, Os) has been studied by computational chemistry. The theoretical study shows that the observed different reactivity can be related to the significant difference in the electron density increase at the central carbon of the allene ligand upon coordination to the metal fragments. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/om700629x |
| 语种 | 英语 |
| WOS记录号 | WOS:000250556900016 |
| 公开日期 | 2013-01-16 |
| 源URL | [http://202.127.28.38/handle/331003/12092]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Bai T,Zhu J,Xue P,et al. Ligand effect on the insertion reactions of allenes with MHCl(CO)(PPh3)(3)and MHCl(PPh3)(3) (M = Ru, Os)[J]. Organometallics,2007,26(23):5581-5589. |
| APA | 白涛.,朱俊.,薛彭.,Ho-Yung Sung.,Ian Duncan Williams.,...&贾国成.(2007).Ligand effect on the insertion reactions of allenes with MHCl(CO)(PPh3)(3)and MHCl(PPh3)(3) (M = Ru, Os).Organometallics,26(23),5581-5589. |
| MLA | 白涛,et al."Ligand effect on the insertion reactions of allenes with MHCl(CO)(PPh3)(3)and MHCl(PPh3)(3) (M = Ru, Os)".Organometallics 26.23(2007):5581-5589. |
入库方式： OAI收割
来源：上海有机化学研究所
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