An unexpected reaction of allylic propynoate under palladium (II) catalysis
文献类型:期刊论文
作者 | Zhang ZG(张兆国) ; Lu XY(陆熙炎) ; Lang SH(郎深慧) |
刊名 | Chin. J. Chem. |
出版日期 | 2002 |
卷号 | 20期号:11页码:1287-1290 |
ISSN号 | 1001-604X |
其他题名 | 在钯(II)催化下丙炔酸烯丙酯的非预期的反应 |
通讯作者 | 陆熙炎 |
英文摘要 | Palladium(II) catalyzed reactions of allyl propynoate in the prsence of excess halide ions with or without allyl halide or acrolein were studied, yielding (E)-3-halo-2-allyl-acrylic acid as the sole product. A mechanism involving halopalladation, carbopalladation, ring opening and β-heteroatom elimination was proposed and was further justified by the reaction with deuterated substrate |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/cjoc.20020201123 |
语种 | 英语 |
公开日期 | 2013-01-22 |
源URL | [http://202.127.28.38/handle/331003/14798] |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Zhang ZG,Lu XY,Lang SH. An unexpected reaction of allylic propynoate under palladium (II) catalysis[J]. Chin. J. Chem.,2002,20(11):1287-1290. |
APA | 张兆国,陆熙炎,&郎深慧.(2002).An unexpected reaction of allylic propynoate under palladium (II) catalysis.Chin. J. Chem.,20(11),1287-1290. |
MLA | 张兆国,et al."An unexpected reaction of allylic propynoate under palladium (II) catalysis".Chin. J. Chem. 20.11(2002):1287-1290. |
入库方式: OAI收割
来源:上海有机化学研究所
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