钯催化反应中的beta-氢消除反应
文献类型：期刊论文
| 作者 | 韩秀玲 ; 刘桂霞 ; 陆熙炎 |
| 刊名 | 有机化学
 |
| 出版日期 | 2005 |
| 卷号 | 25期号:10页码:1182-1197 |
| ISSN号 | 0253-2786 |
| 其他题名 | beta-hydride elimination in palladium-catalyzed reactions cross-coupling reaction; protonolysis; beta-heteroatom elimination |
| 通讯作者 | 陆熙炎 |
| 英文摘要 | Pd(II)-catalyzed reactions were developed using beta-heteroatom elimination and protonolysis reaction to quench the carbon-palladium bond in the presence of halide ions or nitrogen ligands (pyridine, bipyridine, phenanthroline, etc.) for the regeneration of the divalent palladium species. Halide ions or nitrogen ligands are necessary for the catalytic cycle and high yield of the reactions. For Pd(O)-catalyzed reactions, control of beta-hydride elimination is also a challenge for making coupling reactions more diversified. Different kinds of ligands were used to make the coupling reaction suitable for aliphatic compounds. Recently, examples using chloride ion or bathophenanthroline for this purpose were also developed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 语种 | 中文 |
| 公开日期 | 2013-01-22 |
| 源URL | [http://202.127.28.38/handle/331003/14826]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | 韩秀玲,刘桂霞,陆熙炎. 钯催化反应中的beta-氢消除反应[J]. 有机化学,2005,25(10):1182-1197. |
| APA | 韩秀玲,刘桂霞,&陆熙炎.(2005).钯催化反应中的beta-氢消除反应.有机化学,25(10),1182-1197. |
| MLA | 韩秀玲,et al."钯催化反应中的beta-氢消除反应".有机化学 25.10(2005):1182-1197. |
入库方式： OAI收割
来源：上海有机化学研究所
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