Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes
文献类型：期刊论文
| 作者 | Zhang TZ(张唐志) ; Dai LX(戴立信) ; Hou XL(侯雪龙) |
| 刊名 | Tetrahedron-Asymmetry
 |
| 出版日期 | 2007 |
| 卷号 | 18期号:2页码:251-259 |
| ISSN号 | 0957-4166 |
| 其他题名 | 平面手性环蕃单膦配体的合成以及在醛的偶极翻转烯丙基化反应中的应用 |
| 通讯作者 | 侯雪龙 |
| 英文摘要 | Chiral [2.2]paracyclophane monophosphines 8 were synthesized via resolution using chiral palladacycle 10. Chiral phosphinite 5 was also prepared from 4-hydroxy[2.2]paracyclophane. Phosphines 8 and phosphinite 5 were used as the ligand in the umpolung allylation of aldehydes 14 with cyclohexenyl acetate 15, giving homoallyl alcohols 16 in high diastereoselectivity and in moderate to good enantioselectivity. Palladacycle 10 was recovered by treating the palladacycle-phosphine complexes with sodium prolinate, followed by treatment with HCl in high yield. (c) 2007 Elsevier Ltd. All rights reserved. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tetasy.2007.01.020 |
| 语种 | 英语 |
| WOS记录号 | WOS:000245167700013 |
| 公开日期 | 2013-02-19 |
| 源URL | [http://202.127.28.38/handle/331003/15955]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang TZ,Dai LX,Hou XL. Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes[J]. Tetrahedron-Asymmetry,2007,18(2):251-259. |
| APA | 张唐志,戴立信,&侯雪龙.(2007).Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes.Tetrahedron-Asymmetry,18(2),251-259. |
| MLA | 张唐志,et al."Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes".Tetrahedron-Asymmetry 18.2(2007):251-259. |
入库方式： OAI收割
来源：上海有机化学研究所
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