Molecular assembly in an inclusion crystalof tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid
文献类型：期刊论文
| 作者 | Ji BM(吉保明) ; Du CX(杜晨霞) ; Zhu Y(朱玉) ; Ding KL(丁奎岭) |
| 刊名 | J. Chem. Crystallogr.
 |
| 出版日期 | 2000 |
| 卷号 | 30期号:12页码:783-788 |
| ISSN号 | 1074-1542 |
| 其他题名 | 三(2-苯并咪唑甲基)胺与4-硝基苯甲酸的分子晶体种的分子组装 |
| 通讯作者 | 丁奎岭 |
| 英文摘要 | A 1:2 inclusion compound of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid [(C^24H^21N^7).(C^7H&5NO^2)^2] has been prepared and the molecular assembly in solid state has been determined by X-ray crystal structural analysis. The crystal structure (C2/c,a=25.488(5),b=13.304(3),c=21.479(4) A β=93.35(3)°,Z=8,R=0.065) consists of discrete dimeric inclusion compounds joined together by N(5)...N(6) intermolecular hydrogen bonds between pairs of centrosymmetrically related benzimidazole rings of the hosts. There are two types of guest molecules in the crystal, one is incorporated within the cavity of the host via three in tramolecular N-H...O hydrogen bonds while the other is situated outside the cavity and connected with he host through one O-H...N hydrogen bond. The π-π stacking interactions between guests and benzimidazole rings result in one -dimensional columns. The aromatic face-face interactions between neighbouring columns facilitate the assembly of those columns into two-dimensional layers. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1023/A:1013272224434 |
| 语种 | 英语 |
| 公开日期 | 2013-02-22 |
| 源URL | [http://202.127.28.38/handle/331003/17747]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Ji BM,Du CX,Zhu Y,et al. Molecular assembly in an inclusion crystalof tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid[J]. J. Chem. Crystallogr.,2000,30(12):783-788. |
| APA | 吉保明,杜晨霞,朱玉,&丁奎岭.(2000).Molecular assembly in an inclusion crystalof tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid.J. Chem. Crystallogr.,30(12),783-788. |
| MLA | 吉保明,et al."Molecular assembly in an inclusion crystalof tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid".J. Chem. Crystallogr. 30.12(2000):783-788. |
入库方式： OAI收割
来源：上海有机化学研究所
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