Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation
文献类型：期刊论文
| 作者 | Peng XG(彭新高) ; Wang Z(王正) ; Xia CG(夏春谷) ; Ding KL(丁奎岭) |
| 刊名 | Tetrahedron Lett.
 |
| 出版日期 | 2008 |
| 卷号 | 49期号:33页码:4862-4864 |
| ISSN号 | 0040-4039 |
| 其他题名 | Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation |
| 通讯作者 | 丁奎岭 |
| 英文摘要 | A new class of chiral modular bidentate phosphonite ligands has been synthesized in good overall yields by using cheap trans-1,2-diaminocyclohexane and ferrocene as starting materials, and applied in the Rh(I)-catalyzed asymmetric hydroformylation of vinyl acetate and styrene to afford the Corresponding optically active aldehydes with good regioselectivity (up to 16.9 b/l ratio) and moderate to good enantioselectivity (up to 83% ee). The substituents on the backbone of the ligands are found to exhibit a remarkable effect on both the regio- and enantioselectivity of the catalysis. (C) 2008 Elsevier Ltd. All rights reserved. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tetlet.2008.06.012 |
| 语种 | 英语 |
| WOS记录号 | WOS:000258274200013 |
| 公开日期 | 2013-02-22 |
| 源URL | [http://202.127.28.38/handle/331003/17845]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Peng XG,Wang Z,Xia CG,et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation[J]. Tetrahedron Lett.,2008,49(33):4862-4864. |
| APA | 彭新高,王正,夏春谷,&丁奎岭.(2008).Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Lett.,49(33),4862-4864. |
| MLA | 彭新高,et al."Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation".Tetrahedron Lett. 49.33(2008):4862-4864. |
入库方式： OAI收割
来源：上海有机化学研究所
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