Remarkable nucleophilic addition to and ring breaking of the cycloheptatrienyl ligand in reactions of [μ-(1-3-η):(4-7η)-cycloheptatrienyl] tricarbonylirontricarbonylmanganese and-rhenium with aryllithium reagents
文献类型：期刊论文
| 作者 | Xiao N(肖努) ; Qiu ZL(邱志雷) ; Li RH(李荣花) ; Wang BH(王蓓含) ; Xu Q(徐强) ; Sun J(孙杰) ; Chen JB(陈家碧) |
| 刊名 | Organometallics
 |
| 出版日期 | 2002 |
| 卷号 | 21期号:18页码:3709-3715 |
| ISSN号 | 0276-7333 |
| 其他题名 | 环庚三烯配体在μ-(1-3-η):(4-7η)-环庚三烯基铁三羰基锰和铼与芳基锂试剂反应中的不寻常亲核加成和破坏反应 |
| 通讯作者 | 陈家碧 |
| 英文摘要 | The reactions of [μ-(1-3-η):(4-7η)-cycloheptatrienyl] tricarbonylirontricarbonylmanganese, [MnFe{μ-(1-3-η):(4-7η) (CO)^6] (1) with 2 molar equiv of aryllithium reagent, ArLi(Ar=C^6H^5,o-,m-,p-CH^3C^6H^4), in ether at low temperature gave acylmetalate intermediates, followed by alkylation with Et^3OBF^4 in aqueous solution at 0℃ to afford the four novel ring-opened olefine-coordinated tricarbonylirontricarbonylmanganese complexes[MnFe{C^8H&7-(OC^2H^5)Ar}(CO)^6](3,Ar=C^6H^5; 4, Ar=o-CH^3C^6H^4; 5, Ar=mCH^3C66H^4; 6, Ar=p-CH^3C^6H^4).Analogous reactions of [μ-(1-3-η):(4-7η)-cycloheptatrienyl] tricarbonylirontricarbonylrhenium, [ReFe{μ-(1-3-η):(4-7η)-C^7H^7)}(CO)^6] (2), with ArLi(Ar=C^6H^5,o-m-CH^3C^6H^4,p-CF^3C^6H^4)gave the corresponding products[ReFe{C^8H^7(OC^2H^5)Ar}(CO)^6] (7, Ar=C^6H^5; 8, Ar=o-CH^3C^6H^4; 9, Ar=m-CH^3C^6H^4; 10, Ar=p-CF^3C^6H^4), The structures of 4 and 10 have been established by single-crystal X-ray diffraction studies. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/om020328w |
| 语种 | 英语 |
| 公开日期 | 2013-02-27 |
| 源URL | [http://202.127.28.38/handle/331003/21387]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xiao N,Qiu ZL,Li RH,et al. Remarkable nucleophilic addition to and ring breaking of the cycloheptatrienyl ligand in reactions of [μ-(1-3-η):(4-7η)-cycloheptatrienyl] tricarbonylirontricarbonylmanganese and-rhenium with aryllithium reagents[J]. Organometallics,2002,21(18):3709-3715. |
| APA | 肖努.,邱志雷.,李荣花.,王蓓含.,徐强.,...&陈家碧.(2002).Remarkable nucleophilic addition to and ring breaking of the cycloheptatrienyl ligand in reactions of [μ-(1-3-η):(4-7η)-cycloheptatrienyl] tricarbonylirontricarbonylmanganese and-rhenium with aryllithium reagents.Organometallics,21(18),3709-3715. |
| MLA | 肖努,et al."Remarkable nucleophilic addition to and ring breaking of the cycloheptatrienyl ligand in reactions of [μ-(1-3-η):(4-7η)-cycloheptatrienyl] tricarbonylirontricarbonylmanganese and-rhenium with aryllithium reagents".Organometallics 21.18(2002):3709-3715. |
入库方式： OAI收割
来源：上海有机化学研究所
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