A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)
文献类型：期刊论文
| 作者 | Pan RQ(潘瑞琪) ; Liu XX(刘新兴) ; Deng MZ(邓敏智) |
| 刊名 | J. Fluor. Chem.
 |
| 出版日期 | 1999 |
| 卷号 | 95页码:167-170 |
| ISSN号 | 0022-1139 |
| 其他题名 | 一个新型方便地生成α－三氟甲基苯乙烯的方法 |
| 通讯作者 | 邓敏智 |
| 英文摘要 | The suzuki-type coupling reaction of arylboronic acids (1) with 2-bromo-3,3,3-trifluoropropene (2) in the presence of a catalytic amount of dichlorobis(triphenylphosphine)palladium {PdCl=2(PPh=3)=2} and a base can easily give α-(trifluoromethyl)styrenes (3) in good yields. It was also found that 1,2-dibromo-3,3,3-trifluoropropane (4) underwent dehydrobromination in the presence of KOH, and subsequently, palladium-catalyzed cross-coupling with 1 to directly afford 3 in a one pot manner in excellent yields. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/S0022-1139(99)00021-4 |
| 语种 | 英语 |
| 公开日期 | 2013-03-07 |
| 源URL | [http://202.127.28.38/handle/331003/23074]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Pan RQ,Liu XX,Deng MZ. A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)[J]. J. Fluor. Chem.,1999,95:167-170. |
| APA | 潘瑞琪,刘新兴,&邓敏智.(1999).A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3).J. Fluor. Chem.,95,167-170. |
| MLA | 潘瑞琪,et al."A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes (3)".J. Fluor. Chem. 95(1999):167-170. |
入库方式： OAI收割
来源：上海有机化学研究所
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