Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Noncyclopentadienyl Rare-Earth Metal Bis(alkyl) Complexes
文献类型:期刊论文
作者 | Zhang ZC ; Cui DM ; Liu XL |
刊名 | journal of polymer science part a-polymer chemistry
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出版日期 | 2008 |
卷号 | 46期号:20页码:6810-6818 |
关键词 | RING-OPENING POLYMERIZATION LANTHANIDE ALKYL COMPLEXES N AMINO PHOSPHINE-LIGANDS PROPYLENE-OXIDE COORDINATION CATALYST CO2/EPOXIDE COPOLYMERIZATION SALEN COMPLEXES STRUCTURAL-CHARACTERIZATION POLY(PROPYLENE CARBONATE) O MULTIDENTATE LIGANDS |
ISSN号 | 0887-624x |
通讯作者 | cui dm |
中文摘要 | the syntheses of several dialkyl complexes based on rare-earth metal were described. three beta-diimine compounds with varying n-aryl substituents (hl1 = (2-ch3o(c6h4))n=c(ch3)ch=c(ch3)nh(2-ch3o(c6h4)), hl2 = (2,4,6-(ch3)(3) (c6h2))n=c(ch3)ch=c(ch3)nh(2,4,6-(ch3)(3)(c6h2)), hl3 = phn=c(ch3)ch(ch3) nhph) were treated with ln(ch2sime3)(3)(thf)(2) to give dialkyl complexes l(1)ln (ch2sime3)(2) (ln = y (1a), lu (1b), sc (1c)), l(2)ln(ch2sime3)(2)(thf) (ln = y (2a), lu (2b)), and (llu)-lu-3(ch2sime3)(2)(thf) (3). all these complexes were applied to the copolymerization of cyclohexene oxide (cho) and carbon dioxide as single-component catalysts. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000260071300014 |
公开日期 | 2010-04-14 |
源URL | [http://ir.ciac.jl.cn/handle/322003/10511] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang ZC,Cui DM,Liu XL. Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Noncyclopentadienyl Rare-Earth Metal Bis(alkyl) Complexes[J]. journal of polymer science part a-polymer chemistry,2008,46(20):6810-6818. |
APA | Zhang ZC,Cui DM,&Liu XL.(2008).Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Noncyclopentadienyl Rare-Earth Metal Bis(alkyl) Complexes.journal of polymer science part a-polymer chemistry,46(20),6810-6818. |
MLA | Zhang ZC,et al."Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Noncyclopentadienyl Rare-Earth Metal Bis(alkyl) Complexes".journal of polymer science part a-polymer chemistry 46.20(2008):6810-6818. |
入库方式: OAI收割
来源:长春应用化学研究所
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