Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of epsilon-Caprolactone
文献类型：期刊论文
| 作者 | Gao W ; Cui DM ; Liu XM ; Zhang Y ; Mu Y |
| 刊名 | organometallics
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:22页码:5889-5893 |
| 关键词 | RING-OPENING POLYMERIZATION TRIAZACYCLONONANE-AMIDE LIGANDS MONOANIONIC ANCILLARY LIGANDS ETHYLENE-POLYMERIZATION COMPLEXES BEARING ALKYL COMPLEXES HYDRIDE COMPLEXES TRIMETHYLENE CARBONATE METHYL COMPLEXES CYCLIC ESTERS |
| ISSN号 | 0276-7333 |
| 通讯作者 | cui dm |
| 中文摘要 | the tridentate ligand n-(2-((2,6-diisopropylphenylimino)methyl)phenyl)quinolin-8-amine (hl) was prepared. treatment of hl with 1 equiv of ln(ch2sime3)(3)(thf)(2) afforded the corresponding rare-earth metal bis(alkyl) complexes lln(ch2sime3)(2)(thf)(n) (ln = sc, n = 0 (1); y, n = 1 (2); lu, n = 0 (3)) in high yields. variable-temperature h-1 nmr spectral analysis showed that these complexes were fluxional at room temperature. complexes 1 and 3 were thf-free, where the metal center adopted a square-pyramidal geometry, while in 2 the metal center generated a distorted octahedral geometry owing to the coordination of a thf molecule. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000260791400018 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10523]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao W,Cui DM,Liu XM,et al. Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of epsilon-Caprolactone[J]. organometallics,2008,27(22):5889-5893. |
| APA | Gao W,Cui DM,Liu XM,Zhang Y,&Mu Y.(2008).Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of epsilon-Caprolactone.organometallics,27(22),5889-5893. |
| MLA | Gao W,et al."Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of epsilon-Caprolactone".organometallics 27.22(2008):5889-5893. |
入库方式： OAI收割
来源：长春应用化学研究所
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