O-2 activation and hydrolysis of Salan rare-earth metal alkyl complexes
文献类型:期刊论文
作者 | Liu XL ; Cui DM |
刊名 | dalton transactions
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出版日期 | 2008 |
期号 | 28页码:3747-3752 |
关键词 | RING-OPENING POLYMERIZATION TRIS-TERT-BUTYLGALLIUM MOLECULAR-STRUCTURE STRUCTURAL-CHARACTERIZATION OLEFIN POLYMERIZATION CATALYTIC-ACTIVITY CRYSTAL-STRUCTURE LIGANDS REACTIVITY OXIDATION |
ISSN号 | 1477-9226 |
通讯作者 | cui dm |
中文摘要 | salan ligated yttrium alkyl complex 1, (ly)-y-1(ch2sime3)(thf) (salan = l-1: [2-o-3,5-tbu(2)-c6h2ch2n(ch3) ch2](2)), was exposed to an oxygen/ nitrogen atmosphere to give a bimetallic alkoxide complex 4, [(ly)-y-1(mu-och2sime3)](2). whilst the lutetium counterparts 2 ((llu)-lu-1(ch2sime3)(thf)) and 3 ((llu)-lu-2(ch2sime3)(thf); l-2: [2-o-3-tbu-c6h2ch2n(ch3) ch2](2)) were hydrolysed with moist nitrogen to afford mixed hydroxy/silyloxy complexes 5 and 6 ([(llu)-lu-1,2(mu-osime3)(mu-oh) lul1,2]), respectively. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2010-04-14 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/10529] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liu XL,Cui DM. O-2 activation and hydrolysis of Salan rare-earth metal alkyl complexes[J]. dalton transactions,2008(28):3747-3752. |
APA | Liu XL,&Cui DM.(2008).O-2 activation and hydrolysis of Salan rare-earth metal alkyl complexes.dalton transactions(28),3747-3752. |
MLA | Liu XL,et al."O-2 activation and hydrolysis of Salan rare-earth metal alkyl complexes".dalton transactions .28(2008):3747-3752. |
入库方式: OAI收割
来源:长春应用化学研究所
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