Highly cis-1,4 selective polymerization of dienes with homogeneous Ziegler-Natta catalysts based on NCN-pincer rare earth metal dichioride precursors
文献类型：期刊论文
| 作者 | Gao W ; Cui DM |
| 刊名 | journal of the american chemical society
 |
| 出版日期 | 2008 |
| 卷号 | 130期号:14页码:4984-4991 |
| 关键词 | RING-OPENING POLYMERIZATION ISOPRENE POLYMERIZATION STEREOSPECIFIC POLYMERIZATION COMPLEXES BEARING STRUCTURAL-CHARACTERIZATION METHYLALUMINOXANE CATALYST EPSILON-CAPROLACTONE PALLADIUM COMPLEXES METHYL COMPOUNDS ALKYL COMPLEXES |
| ISSN号 | 0002-7863 |
| 通讯作者 | cui dm |
| 中文摘要 | the first aryldiimine ncn-pincer ligated rare earth metal dichlorides (2,6-(2,6-c6h3r2n=ch)(2)c6h3)lncl(2)(thf)(2) (ln = y, r = me (1), et (2), pr (3); r = et, ln = la (4), nd (5), gd (6), sm (7), eu (8), tb (9), dy (10), ho (11), yb (12), lu (13)) were successfully synthesized via transmetalation between 2,6-(2,6-c2h3-r2n=ch)(2)-c6h3li and lncl(3)(thf)(1 similar to 3.5). these complexes are isostructural monomers with two coordinating thf molecules, where the pincer ligand coordinates to the central metal ion in a kappa c:kappa n: kappa n' tridentate mode, adopting a meridional geometry. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000254643900054 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10535]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao W,Cui DM. Highly cis-1,4 selective polymerization of dienes with homogeneous Ziegler-Natta catalysts based on NCN-pincer rare earth metal dichioride precursors[J]. journal of the american chemical society,2008,130(14):4984-4991. |
| APA | Gao W,&Cui DM.(2008).Highly cis-1,4 selective polymerization of dienes with homogeneous Ziegler-Natta catalysts based on NCN-pincer rare earth metal dichioride precursors.journal of the american chemical society,130(14),4984-4991. |
| MLA | Gao W,et al."Highly cis-1,4 selective polymerization of dienes with homogeneous Ziegler-Natta catalysts based on NCN-pincer rare earth metal dichioride precursors".journal of the american chemical society 130.14(2008):4984-4991. |
入库方式： OAI收割
来源：长春应用化学研究所
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