New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene
文献类型：期刊论文
| 作者 | Li SH ; Miao W ; Tang T ; Dong WM ; Zhang XQ ; Cui DM |
| 刊名 | organometallics
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:4页码:718-725 |
| 关键词 | LANTHANIDE ALKYL COMPLEXES STEREOSPECIFIC POLYMERIZATION 1 DIENE POLYMERIZATION METHYL-METHACRYLATE BUTADIENE REACTIVITY COPOLYMERIZATION ETHYLENE NEODYMIUM 3-DIENE POLYMERIZATION |
| ISSN号 | 0276-7333 |
| 通讯作者 | cui dm |
| 中文摘要 | newrareearth metal bis(alkyl) complexes [(npnph)ln(ch2sime3)(2)(thf) (npnph:n(ph)pph2=nc6h2me3-2,4,6; ln = sc (3a), ln = y (3b), ln = lu (3c)) and [(npnpy)sc(ch2sime3)(2)(thf)1 (npnpy = n(py)pph2=nc6h2me3-2,4,6) (3d)) have been prepared via protonolysis reaction between rare earth metal tris(alkyl)s and the corresponding iminophosphonamines. complexes 3a-d are analogous monomers of thf solvate. each metal ion coordinates to a eta(2)-chelated npn ligand and two cis-located alkyl groups, adopting tetrahedron geometry. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000253268000032 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10565]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li SH,Miao W,Tang T,et al. New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene[J]. organometallics,2008,27(4):718-725. |
| APA | Li SH,Miao W,Tang T,Dong WM,Zhang XQ,&Cui DM.(2008).New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene.organometallics,27(4),718-725. |
| MLA | Li SH,et al."New rare earth metal bis(alkyl)s bearing an iminophosphonamido ligand. Synthesis and catalysis toward highly 3,4-selective polymerization of isoprene".organometallics 27.4(2008):718-725. |
入库方式： OAI收割
来源：长春应用化学研究所
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