Theoretical Studies on the Reaction Mechanism of Platinum-Catalyzed Diboration of Allenes
文献类型：期刊论文
| 作者 | Wang MY ; Cheng L ; Wu ZJ |
| 刊名 | organometallics
 |
| 出版日期 | 2008 |
| 卷号 | 27期号:24页码:6464-6471 |
| 关键词 | COPPER(I) BORYL COMPLEXES ENANTIOSELECTIVE DIBORATION DENSITY SILABORATION BONDS MOLECULES ADDITIONS ORBITALS EXCHANGE ALKYNES |
| ISSN号 | 0276-7333 |
| 通讯作者 | wu zj |
| 中文摘要 | the reaction mechanism of pt(0)-catalyzed diboration reaction of allenes is investigated by the density functional method b3lyp. the overall reaction mechanism is examined. the electronic mechanisms of the allene insertion into the pt-b bond are discussed in terms of the electron donation, back-donation, and d-pi interaction. during allene insertion into the pt-b bond, the internal carbon atom of allene is preferred over the terminal one due to the stronger electron back-donation and stronger charge transfer in the former case than that in the latter one. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000261510000017 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10597]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang MY,Cheng L,Wu ZJ. Theoretical Studies on the Reaction Mechanism of Platinum-Catalyzed Diboration of Allenes[J]. organometallics,2008,27(24):6464-6471. |
| APA | Wang MY,Cheng L,&Wu ZJ.(2008).Theoretical Studies on the Reaction Mechanism of Platinum-Catalyzed Diboration of Allenes.organometallics,27(24),6464-6471. |
| MLA | Wang MY,et al."Theoretical Studies on the Reaction Mechanism of Platinum-Catalyzed Diboration of Allenes".organometallics 27.24(2008):6464-6471. |
入库方式： OAI收割
来源：长春应用化学研究所
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