Metal-Dependent Halogenation and/or Coupling Reactions of Porphyrins with PhIX2 (X = Cl, F)
文献类型：期刊论文
| 作者 | Jin LM(金利美) ; Yin JJ(尹娟娟) ; Chen L(陈亮) ; Guo CC(郭灿城) ; Chen QY(陈庆云) |
| 刊名 | Synlett
 |
| 出版日期 | 2005 |
| 期号 | 19页码:2893-2898 |
| ISSN号 | 0936-5214 |
| 其他题名 | PhIX2 (X = Cl, F)作用下卟啉中心金属调节的卤化或偶联反应 |
| 通讯作者 | 郭灿城 ; 陈庆云 |
| 英文摘要 | Treatment of zinc(II)-5,10,15-trisubstituted porphyrins with PhICl2 afforded the corresponding meso-chlorinated porphyrins and meso,meso-linked bisporphyrins in almost 50% yield. The reaction of copper(II), nickel(II), or free-base 5,10,15-trisubstituted porphyrins with PhICl2 gave only meso-chlorinated products without any coupling bisporphyrins. Similarly, the reaction of nickel(II) or free-base 5,15-diphenylporphyrins solely yielded meso-chlorinated products, whereas that of the zinc(II)-5,15-diphenylporphyrin with PhICl2, produced only coupling products. Interestingly, bchloroporphyrins were exclusively formed not only for copper(II) or free-base 5,10,15,20-tetraarylporphyrins, but also for the zinc complexes. In contrast to the reaction of PhICl2, the reaction of PhIF2 with 5,10,15-trisubstituted metalloporphyrins gave the coupling bisporphyrins in high yields, without any fluorinated product. However, in the presence of I2, the meso-iodination of free-base 5,10,15-trisubstituted porphyrins proceeded smoothly. |
| 学科主题 | 有机氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1055/s-2005-918957 |
| 语种 | 英语 |
| 公开日期 | 2013-01-17 |
| 源URL | [http://202.127.28.38/handle/331003/13610]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Jin LM,Yin JJ,Chen L,et al. Metal-Dependent Halogenation and/or Coupling Reactions of Porphyrins with PhIX2 (X = Cl, F)[J]. Synlett,2005(19):2893-2898. |
| APA | 金利美,尹娟娟,陈亮,郭灿城,&陈庆云.(2005).Metal-Dependent Halogenation and/or Coupling Reactions of Porphyrins with PhIX2 (X = Cl, F).Synlett(19),2893-2898. |
| MLA | 金利美,et al."Metal-Dependent Halogenation and/or Coupling Reactions of Porphyrins with PhIX2 (X = Cl, F)".Synlett .19(2005):2893-2898. |
入库方式： OAI收割
来源：上海有机化学研究所
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