Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives
文献类型：期刊论文
| 作者 | Yin JJ(尹娟娟) ; Jin LM(金利美) ; Liu RL(刘瑞丽) ; Li QN(李晴暖) ; Fan CH(樊春海) ; Li Y(李延) ; Li WX(李文新) ; Chen QY(陈庆云) |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2006 |
| 卷号 | 71期号:6页码:2267-2271 |
| ISSN号 | 0022-3263 |
| 其他题名 | 富勒烯和活性有机磷亚甲基试剂的反应：有效合成有机磷取代的C60和C70衍生物 |
| 通讯作者 | 李文新 ; 陈庆云 |
| 英文摘要 | [GRAPHICS] Treatment of C-70 with cycloalkylaminomethylenebisphosphonates in the presence of NaH gave corresponding C-70 dimers 1 in good yield, while the methanofullerenes, C-70 > CH(PO3Et2) (3) and C-70 > C(PO3Et2)(2) (4) or C-60 > CH(PO3Et2) (5) and C-60 > C(PO3Et2)(2) (6), were obtained, respectively, by the reaction of C-70 of C-60 with tetraethyl methylenediphosphonate in the presence of NaH. Diethyl cyanornethylphosphonate reacted with C-60 of C-70 under similar conditions to afford C-60 > C(PO3Et2)CN (7) and C-70 > C(PO3Et2)CN (8). Furthermore, the presence of weak electronic interactions between two fullerene cages of fullerene dimers was demonstrated by cyclic voltammetry. A radical mechanism was proposed for the formation of the fullerene derivatives on the basis of the ESR studies. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jo052263n |
| 语种 | 英语 |
| WOS记录号 | WOS:000236307300009 |
| 公开日期 | 2013-01-17 |
| 源URL | [http://202.127.28.38/handle/331003/13628]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Yin JJ,Jin LM,Liu RL,et al. Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives[J]. J. Org. Chem.,2006,71(6):2267-2271. |
| APA | 尹娟娟.,金利美.,刘瑞丽.,李晴暖.,樊春海.,...&陈庆云.(2006).Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives.J. Org. Chem.,71(6),2267-2271. |
| MLA | 尹娟娟,et al."Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of organophosphorus group substituted C-60 and C-70 derivatives".J. Org. Chem. 71.6(2006):2267-2271. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。