Unexpected formation of N-fluoroalkaneacyl anilides from the reactions of fluoroalkanesulfonyl azides with nitrobenzene and its derivatives
文献类型：期刊论文
| 作者 | Xiong WT(熊婉婷) ; Zhao JW(赵经纬) ; Gu JW(顾继伟) ; Zhu SZ(朱仕正) |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2011 |
| 卷号 | 67期号:29页码:5235-5243 |
| ISSN号 | 0040-4020 |
| 其他题名 | 氟烷基磺酰叠氮与硝基苯及其衍生物反应意外的生成N-氟烷基酰基苯胺类化合物 |
| 通讯作者 | 朱仕正 |
| 英文摘要 | The thermal reactions of fluoroalkanesulfonyl azides R(f)CF(2)SO(2)N(3) 1 with nitrobenzene and its derivatives XC(6)H(4)NO(2) (X=H, F, Cl, CF(3)) gave the unexpected N-fluoroalkaneacyl anilides R(f)CONHC(6)H(4)X (X=H, Cl, F, CF3) in addition to fluoroalkanesulfonyl amides R(f)CF(2)SO(2)NH(2). Under the same reaction conditions, however, nitrobenzene containing an electron-donating group RC(6)H(4)NO(2) (R=CH(3), OCH(3)) reacted with 1 affording the corresponding N-fluoroalkanesulfonyl anilides R(f)CF(2)SO(2)NHC(6)H(3)(NO(2))R. Other electron-poor benzene derivatives, such as benzaldehyde, benzoate, and acetophenone C(6)H(5)Y(Y=CHO, COCH(3), CO(2)CH(3)) all gave the meta-substituted N-fluoroalkanesulfonyl anilides R(f)CF(2)SO(2)NHC(6)H(4)Y. (C) 2011 Elsevier Ltd. All rights reserved. |
| 学科主题 | 有机氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tet.2011.05.027 |
| 语种 | 英语 |
| WOS记录号 | WOS:000292472300015 |
| 公开日期 | 2013-01-18 |
| 源URL | [http://202.127.28.38/handle/331003/14520]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Xiong WT,Zhao JW,Gu JW,et al. Unexpected formation of N-fluoroalkaneacyl anilides from the reactions of fluoroalkanesulfonyl azides with nitrobenzene and its derivatives[J]. Tetrahedron,2011,67(29):5235-5243. |
| APA | 熊婉婷,赵经纬,顾继伟,&朱仕正.(2011).Unexpected formation of N-fluoroalkaneacyl anilides from the reactions of fluoroalkanesulfonyl azides with nitrobenzene and its derivatives.Tetrahedron,67(29),5235-5243. |
| MLA | 熊婉婷,et al."Unexpected formation of N-fluoroalkaneacyl anilides from the reactions of fluoroalkanesulfonyl azides with nitrobenzene and its derivatives".Tetrahedron 67.29(2011):5235-5243. |
入库方式： OAI收割
来源：上海有机化学研究所
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