中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination

文献类型:期刊论文

作者Shen YC(沈延昌) ; Ni JH(倪家宏) ; Li P(李平) ; Sun J(孙杰)
刊名J. Chem. Soc.-Perkin Trans. 1
出版日期1999
页码509-512
ISSN号0300-922X
其他题名“一锅法”立体选择性地合成三氟甲基(2Z, 4E)-戊二烯腈通过双烯化反应
通讯作者沈延昌
英文摘要A novel double olefination via sequential transformation of diethyl(1-cyanoethyl)phosphonate and its application to the synthesis of substituted trifluoromethylated pentadienenitriles with 2Z,4E-isomers formed exclusively in 71--85% yield are described. This reaction is of broad scope since R may be alkyl, aryl or a heterocyclic group. The configuration of the products was ascertained on the basis of X-ray crystallographic analysis. The stereochemical results are rationalized by the proposed mechanism.
学科主题氟化学
收录类别SCI
原文出处http://dx.doi.org/10.1039/a808147f
语种英语
公开日期2013-02-21
源URL[http://202.127.28.38/handle/331003/16945]  
专题上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式
GB/T 7714
Shen YC,Ni JH,Li P,et al. One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination[J]. J. Chem. Soc.-Perkin Trans. 1,1999:509-512.
APA 沈延昌,倪家宏,李平,&孙杰.(1999).One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination.J. Chem. Soc.-Perkin Trans. 1,509-512.
MLA 沈延昌,et al."One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination".J. Chem. Soc.-Perkin Trans. 1 (1999):509-512.

入库方式: OAI收割

来源:上海有机化学研究所

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