One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination
文献类型：期刊论文
| 作者 | Shen YC(沈延昌) ; Ni JH(倪家宏) ; Li P(李平) ; Sun J(孙杰) |
| 刊名 | J. Chem. Soc.-Perkin Trans. 1
 |
| 出版日期 | 1999 |
| 页码 | 509-512 |
| ISSN号 | 0300-922X |
| 其他题名 | “一锅法”立体选择性地合成三氟甲基(2Z, 4E)－戊二烯腈通过双烯化反应 |
| 通讯作者 | 沈延昌 |
| 英文摘要 | A novel double olefination via sequential transformation of diethyl(1-cyanoethyl)phosphonate and its application to the synthesis of substituted trifluoromethylated pentadienenitriles with 2Z,4E-isomers formed exclusively in 71--85% yield are described. This reaction is of broad scope since R may be alkyl, aryl or a heterocyclic group. The configuration of the products was ascertained on the basis of X-ray crystallographic analysis. The stereochemical results are rationalized by the proposed mechanism. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/a808147f |
| 语种 | 英语 |
| 公开日期 | 2013-02-21 |
| 源URL | [http://202.127.28.38/handle/331003/16945]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Shen YC,Ni JH,Li P,et al. One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination[J]. J. Chem. Soc.-Perkin Trans. 1,1999:509-512. |
| APA | 沈延昌,倪家宏,李平,&孙杰.(1999).One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination.J. Chem. Soc.-Perkin Trans. 1,509-512. |
| MLA | 沈延昌,et al."One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination".J. Chem. Soc.-Perkin Trans. 1 (1999):509-512. |
入库方式： OAI收割
来源：上海有机化学研究所
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