Stereocontrolled synthesis of fluorinated (E)-or(Z)-allylic phosphonates
文献类型：期刊论文
| 作者 | Shen YC(沈延昌) ; Zhang YM(张玉民) ; Zhang ZH(张增洪) |
| 刊名 | Synthesis
 |
| 出版日期 | 2000 |
| 期号 | 11页码:1535-1538 |
| ISSN号 | 0039-7881 |
| 其他题名 | 立体控制合成E-或Z-稀炳基膦酸酯 |
| 通讯作者 | 沈延昌 |
| 英文摘要 | Treatment of (dicarbonylmethylene)triphenylphosphoranes 1 with [(diethoxylphosphinoyl)methyl]lithium (2a)gave 3a, followed by protonation and elimination of triphenylphosphine oxide, to afford the Z-isomer exclusively (4b,4e,4f,4g); while [(dialkoxyphosphinoly)alkyl]lithium (2b) reacted with 1 under the same conditions, to give the E-isomers exclusively (4a,4c,4d) or predominantly (4h,4i,4j). Thus this methodology provides a stereocontrolled synthesis of the title compounds. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1055/s-2000-7596 |
| 语种 | 英语 |
| 公开日期 | 2013-02-21 |
| 源URL | [http://202.127.28.38/handle/331003/16959]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Shen YC,Zhang YM,Zhang ZH. Stereocontrolled synthesis of fluorinated (E)-or(Z)-allylic phosphonates[J]. Synthesis,2000(11):1535-1538. |
| APA | 沈延昌,张玉民,&张增洪.(2000).Stereocontrolled synthesis of fluorinated (E)-or(Z)-allylic phosphonates.Synthesis(11),1535-1538. |
| MLA | 沈延昌,et al."Stereocontrolled synthesis of fluorinated (E)-or(Z)-allylic phosphonates".Synthesis .11(2000):1535-1538. |
入库方式： OAI收割
来源：上海有机化学研究所
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