One-pot synthesis of trifluoromethylated 4-cyanoalka-1,4-dienes with predominant Z-selectivity trifluoromethylated 4-cyano-alka-1,4-dienes; Z-selectivity
文献类型：期刊论文
| 作者 | Shen YC(沈延昌) ; Wang GP(王国平) |
| 刊名 | Synth. Commun.
 |
| 出版日期 | 2005 |
| 卷号 | 35期号:19页码:2521-2527 |
| ISSN号 | 0039-7911 |
| 其他题名 | “一锅”法合成主要具有Z-选择性的三氟甲基-4-氰基双烯烃 |
| 英文摘要 | The consecutive reaction of diethyl (1-cyanobut-3-enyl)phosphonate with n-butyllithium, trifluoroacetic anhydride, and Grignard reagents gave trifluoromethylated 4-cyano-alka-1,4-dienes in 45-89% yields with predominant Z-selectivity (Z: E = 89-78: 11 :22). Two isomers could be easily separated by column chromatography. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1080/00397910500212841 |
| 语种 | 英语 |
| 公开日期 | 2013-02-21 |
| 源URL | [http://202.127.28.38/handle/331003/17021]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Shen YC,Wang GP. One-pot synthesis of trifluoromethylated 4-cyanoalka-1,4-dienes with predominant Z-selectivity trifluoromethylated 4-cyano-alka-1,4-dienes; Z-selectivity[J]. Synth. Commun.,2005,35(19):2521-2527. |
| APA | 沈延昌,&王国平.(2005).One-pot synthesis of trifluoromethylated 4-cyanoalka-1,4-dienes with predominant Z-selectivity trifluoromethylated 4-cyano-alka-1,4-dienes; Z-selectivity.Synth. Commun.,35(19),2521-2527. |
| MLA | 沈延昌,et al."One-pot synthesis of trifluoromethylated 4-cyanoalka-1,4-dienes with predominant Z-selectivity trifluoromethylated 4-cyano-alka-1,4-dienes; Z-selectivity".Synth. Commun. 35.19(2005):2521-2527. |
入库方式： OAI收割
来源：上海有机化学研究所
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