Grown-like macrocycle zinc complex derived from beta-diketone ligand for the polymerization of rac-lactide
文献类型：期刊论文
| 作者 | Pang X ; Chen XS ; Zhuang XL ; Jing XB |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 46期号:2页码:643-649 |
| 关键词 | RING-OPENING POLYMERIZATION RACEMIC LACTIDE STEREOSELECTIVE POLYMERIZATION CYCLIC ESTERS LIVING POLYMERIZATION METAL-COMPLEXES INITIATOR STEREOCONTROL COPOLYMERS MECHANISM |
| ISSN号 | 0887-624x |
| 通讯作者 | chen xs |
| 中文摘要 | enolic schiff base zinc (ii) complex 1 was synthesized. xrd revealed 1 was a novel crown-like macrocycle structure consisted of hexanuclear units of (lznet)(6) via the coordination chelation between the zn atom and adjacent amine nitrogen atom. further reaction of 1 with one equivalent 2-propanol at rt produced zn-alkoxide 2 by in situ alcoholysis. complex 2 was used as an initiator to polymerize rac-lactide in a controlled manner to give heterotactic enriched polylactide. factors that influenced the polymerization such as the polymerization time and the temperature as well as the monomer concentration were discussed in detail in this paper. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000252473000023 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10767]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Pang X,Chen XS,Zhuang XL,et al. Grown-like macrocycle zinc complex derived from beta-diketone ligand for the polymerization of rac-lactide[J]. journal of polymer science part a-polymer chemistry,2008,46(2):643-649. |
| APA | Pang X,Chen XS,Zhuang XL,&Jing XB.(2008).Grown-like macrocycle zinc complex derived from beta-diketone ligand for the polymerization of rac-lactide.journal of polymer science part a-polymer chemistry,46(2),643-649. |
| MLA | Pang X,et al."Grown-like macrocycle zinc complex derived from beta-diketone ligand for the polymerization of rac-lactide".journal of polymer science part a-polymer chemistry 46.2(2008):643-649. |
入库方式： OAI收割
来源：长春应用化学研究所
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