Highly efficient and recoverable dendritic organocatalyst from click chemistry for the asymmetric michael addition of ketones to nitroolefins without the use of organic solvent
文献类型:期刊论文
作者 | Lv GH ; Jin RH ; Mai WP ; Gao LX |
刊名 | tetrahedron-asymmetry
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出版日期 | 2008 |
卷号 | 19期号:22页码:2568-2572 |
关键词 | CHIRAL IONIC LIQUID DIELS-ALDER REACTIONS ALDOL REACTION RECYCLABLE ORGANOCATALYST SUPPORTED ORGANOCATALYST L-PROLINE PYRROLIDINE SULFONAMIDE ENANTIOSELECTIVE ALDOL WATER ALDEHYDES |
ISSN号 | 0957-4166 |
通讯作者 | gao lx |
中文摘要 | a series of pyrrolidine-triazole based dendritic catalysts have been synthesized and applied directly in the asymmetric michael addition of ketones to nitroolefins without the use of an organic solvent. good yields (up to 99%), and high diastereoselectivities (up to syn/anti = 45:1) and enantioselectivities (up to 95% ee) have been obtained. furthermore. the third generation catalyst can be reused at least five times without significant loss of catalytic activity. (c) 2008 elsevier ltd. all rights reserved. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000262053900017 |
公开日期 | 2010-04-14 |
源URL | [http://ir.ciac.jl.cn/handle/322003/10785] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Lv GH,Jin RH,Mai WP,et al. Highly efficient and recoverable dendritic organocatalyst from click chemistry for the asymmetric michael addition of ketones to nitroolefins without the use of organic solvent[J]. tetrahedron-asymmetry,2008,19(22):2568-2572. |
APA | Lv GH,Jin RH,Mai WP,&Gao LX.(2008).Highly efficient and recoverable dendritic organocatalyst from click chemistry for the asymmetric michael addition of ketones to nitroolefins without the use of organic solvent.tetrahedron-asymmetry,19(22),2568-2572. |
MLA | Lv GH,et al."Highly efficient and recoverable dendritic organocatalyst from click chemistry for the asymmetric michael addition of ketones to nitroolefins without the use of organic solvent".tetrahedron-asymmetry 19.22(2008):2568-2572. |
入库方式: OAI收割
来源:长春应用化学研究所
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