Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups
文献类型：期刊论文
| 作者 | Zheng Y ; Pan L ; Li YG ; Li YS |
| 刊名 | european polymer journal
 |
| 出版日期 | 2008 |
| 卷号 | 44期号:2页码:475-482 |
| 关键词 | CHAIN TRANSFER-REACTION MEDIATED OLEFIN POLYMERIZATION ETHYLENE POLYMERIZATION CATALYZED COPOLYMERIZATION METALLOCENE CATALYSIS TRANSPORT-PROPERTIES METHYL ACRYLATE BLOCK-COPOLYMER P-METHYLSTYRENE POLAR MONOMERS |
| ISSN号 | 0014-3057 |
| 通讯作者 | li ys |
| 中文摘要 | the strong polar group, sulfonic acid, has successfully been introduced into ethylene/allylbenzene copolymers without degradation or crosslinking via chlorosulfonation reaction with chlorosulfonic acid as a chlorosulforiating agent in 1, 1,2,2-tetrachloroethane followed by hydrolysis. the degree of sulforiation (ds) can be easily controlled by changing the ratio of chlorosulfonic acid to the pendant phenyls of the copolymer. the microstructure of sulfonated copolymers were unambiguously revealed by h-1 nmr and h-1-h-1 cosy spectral analyses, which indicates that all the sulforiation reactions exclusively took place at the para-position of the aromatic rings. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000254116500021 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10883]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zheng Y,Pan L,Li YG,et al. Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups[J]. european polymer journal,2008,44(2):475-482. |
| APA | Zheng Y,Pan L,Li YG,&Li YS.(2008).Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups.european polymer journal,44(2),475-482. |
| MLA | Zheng Y,et al."Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups".european polymer journal 44.2(2008):475-482. |
入库方式： OAI收割
来源：长春应用化学研究所
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