Branched polystyrene with abundant pendant vinyl functional groups from asymmetric divinyl monomer
文献类型：期刊论文
| 作者 | Dong ZM ; Liu XH ; Lin Y ; Li YS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 46期号:18页码:6023-6034 |
| 关键词 | TRANSFER RAFT POLYMERIZATION INCORPORATION RADICAL COPOLYMERIZATION ETHYLENE-GLYCOL DIMETHACRYLATE LIVING ANIONIC-POLYMERIZATION SOLUBLE HYPERBRANCHED POLYMER CHAIN TRANSFER POLYMERIZATION POLY(METHYL METHACRYLATE)S METHYL-METHACRYLATE STAR POLYMERS END-GROUPS |
| ISSN号 | 0887-624x |
| 通讯作者 | li ys |
| 中文摘要 | branched polystyrenes with abundant pendant vinyl functional groups were prepared via radical polymerization of an asymmetric divinyl monomer, which possesses a higher reactive styryl and a lower reactive butenyl. employing a fast reversible addition fragmentation chain transfer (raft) equilibrium, the concentration of active propagation chains remained at a low value and thus crosslinking did not occur until a high level of monomer conversion. the combination of a higher reaction temperature (120 degrees c) and raft agent cumyl dithiobenzoate was demonstrated to be optimal for providing both a more highly branched architecture and a higher polymer yield. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259325100006 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10903]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Dong ZM,Liu XH,Lin Y,et al. Branched polystyrene with abundant pendant vinyl functional groups from asymmetric divinyl monomer[J]. journal of polymer science part a-polymer chemistry,2008,46(18):6023-6034. |
| APA | Dong ZM,Liu XH,Lin Y,&Li YS.(2008).Branched polystyrene with abundant pendant vinyl functional groups from asymmetric divinyl monomer.journal of polymer science part a-polymer chemistry,46(18),6023-6034. |
| MLA | Dong ZM,et al."Branched polystyrene with abundant pendant vinyl functional groups from asymmetric divinyl monomer".journal of polymer science part a-polymer chemistry 46.18(2008):6023-6034. |
入库方式： OAI收割
来源：长春应用化学研究所
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