Ethylene Polymerization of the New Titanium Complexes Bearing a Phosphine Oxide-Bridged Bisphenolato Ligand
文献类型:期刊论文
作者 | He LP ; Liu JY ; Pan L ; Li YS |
刊名 | journal of polymer science part a-polymer chemistry
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出版日期 | 2008 |
卷号 | 46期号:21页码:7062-7073 |
关键词 | IMINE CHELATE LIGANDS OLEFIN POLYMERIZATION ZIRCONIUM COMPLEXES BIS(PHENOLATO) LIGAND TI COMPLEX CATALYSTS COPOLYMERIZATION PROPYLENE BEHAVIOR METHYLALUMINOXANE |
ISSN号 | 0887-624x |
通讯作者 | li ys |
中文摘要 | a series of novel titanium(iv) complexes combining a phosphine oxide-bridged bisphenolato ligand ticl2{2,2'-o=p-r-3 (4-r-2-6-r-1-c6h2o)(2)}(thf) (6a: r-1 = tbu, r-2 - h, r-3 ph; 6b: r-1 - ph, r-2 = h, r-3 = ph; 6c: r-1 = r-2 = tbu, r-3 = ph; 6d: r-1 = r-2 cumyl, r-3 = ph; 6e: r-1 = tbu, r-2 = h, r-3 = phf5) were prepared by the reaction of corresponding bisphenolato ligands with ticl4 in thf. x-ray analysis reveals that complex 6a adopts distorted octahedral geometry around the titanium center. these catalysts were performed for ethylene polymerization in the presence of modified methyaluminoxane (mmao). |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000260587100019 |
公开日期 | 2010-04-14 |
源URL | [http://ir.ciac.jl.cn/handle/322003/10907] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | He LP,Liu JY,Pan L,et al. Ethylene Polymerization of the New Titanium Complexes Bearing a Phosphine Oxide-Bridged Bisphenolato Ligand[J]. journal of polymer science part a-polymer chemistry,2008,46(21):7062-7073. |
APA | He LP,Liu JY,Pan L,&Li YS.(2008).Ethylene Polymerization of the New Titanium Complexes Bearing a Phosphine Oxide-Bridged Bisphenolato Ligand.journal of polymer science part a-polymer chemistry,46(21),7062-7073. |
MLA | He LP,et al."Ethylene Polymerization of the New Titanium Complexes Bearing a Phosphine Oxide-Bridged Bisphenolato Ligand".journal of polymer science part a-polymer chemistry 46.21(2008):7062-7073. |
入库方式: OAI收割
来源:长春应用化学研究所
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