Fixation of carbon dioxide into aliphatic polycarbonate, cobalt porphyrin catalyzed regio-specific poly(propylene carbonate) with high molecular weight
文献类型：期刊论文
| 作者 | Qin YS ; Wang XH ; Zhang SB ; Zhao XJ ; Wang FS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 46期号:17页码:5959-5967 |
| 关键词 | PROPYLENE-OXIDE ALTERNATING COPOLYMERIZATION CYCLIC CARBONATE METAL-COMPLEXES CYCLOHEXENE OXIDE POLYMER SYNTHESIS SALEN COMPLEXES CO2 EPOXIDES EFFICIENT |
| ISSN号 | 0887-624x |
| 通讯作者 | wang xh |
| 中文摘要 | cobalt porphyrin complex ((tppcox)-x-iii) (tpp = 5, 10, 15, 20-tetraphenylporphyrin; x = halide) in combination with ionic organic ammonium salt was used for the regio-specific copolymerization of propylene oxide and carbon dioxide. a turnover frequency of 188 h(-1) was achieved after 5 h, and the byproduct propylene carbonate was successfully controlled to below 1%, where the obtained poly(propylene carbonate) (ppc) showed number average molecular weight (m-n) of 48 kg/mol, head-to-tail content of 93%, and carbonate linkage of over 99%. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000258981000023 |
| 公开日期 | 2010-04-14 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/10993]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qin YS,Wang XH,Zhang SB,et al. Fixation of carbon dioxide into aliphatic polycarbonate, cobalt porphyrin catalyzed regio-specific poly(propylene carbonate) with high molecular weight[J]. journal of polymer science part a-polymer chemistry,2008,46(17):5959-5967. |
| APA | Qin YS,Wang XH,Zhang SB,Zhao XJ,&Wang FS.(2008).Fixation of carbon dioxide into aliphatic polycarbonate, cobalt porphyrin catalyzed regio-specific poly(propylene carbonate) with high molecular weight.journal of polymer science part a-polymer chemistry,46(17),5959-5967. |
| MLA | Qin YS,et al."Fixation of carbon dioxide into aliphatic polycarbonate, cobalt porphyrin catalyzed regio-specific poly(propylene carbonate) with high molecular weight".journal of polymer science part a-polymer chemistry 46.17(2008):5959-5967. |
入库方式： OAI收割
来源：长春应用化学研究所
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