Influence of compressed carbon dioxide on hydrogenation reactions in cyclohexane with a Pd/C catalyst
文献类型:期刊论文
作者 | Hao JM ; Xi CY ; Cheng HY ; Liu RX ; Cai SX ; Arai M ; Zhao FY |
刊名 | industrial & engineering chemistry research
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出版日期 | 2008 |
卷号 | 47期号:17页码:6796–6800 |
关键词 | GAS-EXPANDED LIQUIDS SELECTIVE HYDROGENATION CO2-EXPANDED SOLVENTS HETEROGENEOUS CATALYSIS SUPERCRITICAL FLUIDS SOLUBILITY MEDIA PRESSURIZATION CINNAMALDEHYDE NITROBENZENE |
ISSN号 | 0888-5885 |
通讯作者 | zhao fy |
中文摘要 | the potential of co2-expanded liquid media for chemical reactions has been examined in this work, using cyclohexane as a solvent and pd/c as a heterogeneous catalyst for hydrogenation of styrene, citral, and nitrobenzene with h-2. the rate of hydrogenation reactions is increased, and the product selectivity is altered in the co2-expanded cyclohexane phase. in the hydrogenation of citral, the selectivity to citronellal decreases with co2 pressure, which changes from similar to 80% in the neat cyclohexane to similar to 65% at 16 mpa. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000258777700054 |
公开日期 | 2010-04-14 |
源URL | [http://ir.ciac.jl.cn/handle/322003/11037] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Hao JM,Xi CY,Cheng HY,et al. Influence of compressed carbon dioxide on hydrogenation reactions in cyclohexane with a Pd/C catalyst[J]. industrial & engineering chemistry research,2008,47(17):6796–6800. |
APA | Hao JM.,Xi CY.,Cheng HY.,Liu RX.,Cai SX.,...&Zhao FY.(2008).Influence of compressed carbon dioxide on hydrogenation reactions in cyclohexane with a Pd/C catalyst.industrial & engineering chemistry research,47(17),6796–6800. |
MLA | Hao JM,et al."Influence of compressed carbon dioxide on hydrogenation reactions in cyclohexane with a Pd/C catalyst".industrial & engineering chemistry research 47.17(2008):6796–6800. |
入库方式: OAI收割
来源:长春应用化学研究所
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