中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme

文献类型:期刊论文

作者Ding, Jiawang; Lv, Enguang; Zhu, Liyan; Qin, Wei1
刊名ANALYTICAL CHEMISTRY
出版日期2017-03-21
卷号89期号:6页码:3235-3239
关键词ELECTROGENERATED CHEMILUMINESCENCE POTENTIOMETRIC SENSORS SELECTIVE ELECTRODES MEMBRANE ELECTRODES GOLD NANOPARTICLES OPTODES HEPARIN SYSTEMS
ISSN号0003-2700
产权排序[Qin, Wei] Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China; YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
通讯作者Qin, W (reprint author), Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn
英文摘要We report here on an optical ion sensing platform, in which a polymeric membrane ion-selective electrode (ISE) serves as not only a potentiometric transducer for ion activities in the sample solution but also a reference electrode for the potential-modulated release of enzyme from an iron alginate-horseradish peroxidase (HRP) thin film modified working electrode. The ISE and working electrode are physically separated by a salt bridge: The dissolution of the HRP-embedded thin film can be triggered by the reduction of Fe3+, which is modulated by the potential response of the ISE to the target ion in the sample. The released enzyme induces the, oxidation of its substrate mediated by H2O2, to produce a visual color change. With this setup, an optical ion sensing platform for both cations (e.g., NH4+) and anions,(e.g., Cl-) can be obtained. The proposed platform provides a general and versatile visual-sensing strategy for ions and allows optical ion sensing in colored and turbid solutions.
学科主题Chemistry
研究领域[WOS]Chemistry
关键词[WOS]ELECTROGENERATED CHEMILUMINESCENCE ; POTENTIOMETRIC SENSORS ; SELECTIVE ELECTRODES ; MEMBRANE ELECTRODES ; GOLD NANOPARTICLES ; OPTODES ; HEPARIN ; SYSTEMS
收录类别SCI
原文出处10.1021/acs.analchem.7b00072
语种英语
WOS记录号WOS:000397478300001
源URL[http://ir.yic.ac.cn/handle/133337/22062]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位1.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China
2.YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
推荐引用方式
GB/T 7714
Ding, Jiawang,Lv, Enguang,Zhu, Liyan,et al. Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme[J]. ANALYTICAL CHEMISTRY,2017,89(6):3235-3239.
APA Ding, Jiawang,Lv, Enguang,Zhu, Liyan,&Qin, Wei.(2017).Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme.ANALYTICAL CHEMISTRY,89(6),3235-3239.
MLA Ding, Jiawang,et al."Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme".ANALYTICAL CHEMISTRY 89.6(2017):3235-3239.

入库方式: OAI收割

来源:烟台海岸带研究所

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