An All-solid-state Polymeric Membrane Ca2+-selective Electrode Based on Hydrophobic Alkyl-chain-functionalized Graphene Oxide
文献类型：期刊论文
| 作者 | Yin, Tanji1,2 ; Li, Jinghui1,2,3; Qin, Wei1,2
|
| 刊名 | ELECTROANALYSIS
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 29期号:3页码:821-827 |
| 关键词 | All-solid-state ion-selective electrode Ionophore immobilization Graphene |
| ISSN号 | 1040-0397 |
| 产权排序 | [Yin, Tanji; Li, Jinghui; Qin, Wei] Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Beijing 100864, Peoples R China; [Yin, Tanji; Li, Jinghui; Qin, Wei] YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China; [Li, Jinghui] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 通讯作者 | Yin, TJ (reprint author), Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Beijing 100864, Peoples R China. ; Yin, TJ (reprint author), YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China. tjyin@yic.ac.cn |
| 英文摘要 | An all-solid-state polymeric membrane Ca2+-selective electrode based on hydrophobic octadecylamine-functionalized graphene oxide has been developed. The hydrophobic composite in the ion-selective membrane not only acts as a transduction element to improve the potential stability for the all-solid-state Ca2+-selective electrode, but also is used to immobilize Ca2+ ionophore with lipophilic side chains through hydrophobic interactions. The developed all-solid-state Ca2+-selective electrode shows a stable potential response in the linear range of 3.0x10(-7)-1.0x10(-3)M with a slope of 24.7 +/- 0.3mV/dec, and the detection limit is (1.6 +/- 0.2 )x10(-7)M (n=3). Additionally, due to the hydrophobicity and electrical conductivity of the composite, the proposed all-solid-state ion-selective electrode exhibits an improved stability with the absence of water layer between the ion-selective membrane and the underlying glassy carbon electrode. This work provides a simple, efficient and low-cost methodology for developing stable and robust all-solid-state ion-selective electrode with ionophore immobilization. |
| 学科主题 | Chemistry; Electrochemistry |
| 研究领域[WOS] | Chemistry ; Electrochemistry |
| 关键词[WOS] | ION-SELECTIVE ELECTRODES ; POTENTIOMETRIC SENSORS ; CARBON NANOTUBES ; DETECTION LIMIT ; BULK OPTODES ; IONOPHORE ; CONTACT ; TRANSDUCERS ; NANOPARTICLES ; BEHAVIOR |
| 收录类别 | SCI |
| 原文出处 | 10.1002/elan.201600383 |
| 语种 | 英语 |
| WOS记录号 | WOS:000395770500023 |
| 源URL | [http://ir.yic.ac.cn/handle/133337/22066]  |
| 专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 烟台海岸带研究所_近岸生态与环境实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Beijing 100864, Peoples R China 2.YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, Tanji,Li, Jinghui,Qin, Wei. An All-solid-state Polymeric Membrane Ca2+-selective Electrode Based on Hydrophobic Alkyl-chain-functionalized Graphene Oxide[J]. ELECTROANALYSIS,2017,29(3):821-827. |
| APA | Yin, Tanji,Li, Jinghui,&Qin, Wei.(2017).An All-solid-state Polymeric Membrane Ca2+-selective Electrode Based on Hydrophobic Alkyl-chain-functionalized Graphene Oxide.ELECTROANALYSIS,29(3),821-827. |
| MLA | Yin, Tanji,et al."An All-solid-state Polymeric Membrane Ca2+-selective Electrode Based on Hydrophobic Alkyl-chain-functionalized Graphene Oxide".ELECTROANALYSIS 29.3(2017):821-827. |
入库方式： OAI收割
来源：烟台海岸带研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。