Novel Re(I) dendrimers: synthesis, characterization and theoretical studies
文献类型：期刊论文
| 作者 | Si ZJ ; Li XN ; Li XY ; Xu GH ; Pan CL ; Guo ZY ; Zhang HJ ; Zhou L |
| 刊名 | dalton transactions
 |
| 出版日期 | 2009 |
| 期号 | 47页码:10592-10600 |
| 关键词 | DENSITY-FUNCTIONAL THEORY RHENIUM(I) TRICARBONYL COMPLEXES TRANSITION-METAL COMPLEXES PHOTOPHYSICAL PROPERTIES RU(II) COMPLEXES REDUCTION LIGANDS SYSTEMS PHOTOCHEMISTRY SPECTROSCOPY |
| ISSN号 | 1477-9226 |
| 通讯作者 | zhang hj |
| 中文摘要 | four novel diimine rhenium(i) carbonyl complexes with the formula [re(co)(3)(l) br], where l = 2-(4-(9h-carbazol-9-yl) phenyl)-1h-imidazo[4,5-f][1,10] phenanthroline (p1), 2-(4-(3,6-di-tert-butyl-9h-carbazol-9-yl) phenyl)-1h-imidazo-[4,5-f][1,10] phenanthroline (p2), 2-(4-(6-(9h-carbazol-9-yl)-9h-3,9'-bicarbazol-9-yl) phenyl)-1h-imidazo[4,5-f][1,10] phenanthroline (d1), and 2-(4-(3', 6'-di-tert-butyl-6-(3,6-di-tert-butyl-9h-carbazol-9-yl)-9h-3,9'-bicarbazol-9-yl) phenyl)-1h-imidazo[4,5-f][1,10] phenanthroline (d2), have been successfully synthesized and fully characterized by (hnmr)-h-1, ir, and uv-vis, etc. the luminescence quantum yields (lqys) of the parent re(i) complexes p1 and p2 are 0.13 and 0.16, respectively, which are much higher than the previously reported re(i) dendrimers. the homos and the lumos of p1 and p2 are calculated to be mainly composed of [d(re) + pi(co + br)] and pi*(l) orbital, respectively. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272193900027 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/11289]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Si ZJ,Li XN,Li XY,et al. Novel Re(I) dendrimers: synthesis, characterization and theoretical studies[J]. dalton transactions,2009(47):10592-10600. |
| APA | Si ZJ.,Li XN.,Li XY.,Xu GH.,Pan CL.,...&Zhou L.(2009).Novel Re(I) dendrimers: synthesis, characterization and theoretical studies.dalton transactions(47),10592-10600. |
| MLA | Si ZJ,et al."Novel Re(I) dendrimers: synthesis, characterization and theoretical studies".dalton transactions .47(2009):10592-10600. |
入库方式： OAI收割
来源：长春应用化学研究所
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